Qiu Liyou, Liang Bin, Jiang Like(Department of Chemical Engineering. INVESTIGATION ON THE SOLID STATE REDUCTION OF FLUORAPATITE[J]. CIESC Journal, 1996, (1).
Qiu Liyou, Liang Bin, Jiang Like(Department of Chemical Engineering. INVESTIGATION ON THE SOLID STATE REDUCTION OF FLUORAPATITE[J]. CIESC Journal, 1996, (1).DOI:
The reaction mechanism and rate-controlling step for the carbon reduction of fluorapatite were investigated with the shaped feeds of fluorapatite
silica(AR)and active carbon(reagent)Powders.The reaction mechanism is suggested as that 2C_a F_2 SiO_2 and Ca_3(PO_4)_2are formed in the defluorination between f1uorapatite and silica
and then the Ca_3(PO_4)_2 diffuses through the molten liquid onto the surface of carbon particle where it is reduced by carbon.The steps are The fluor is evolved in the form of SiF_4 at a higher silica-lime molar ratio.When the silica-lime molar ratio is rather lower
the fluor remains in the residue in the form of 2CaF_2·SiO_2.