李平, 许志宏. A MODIFIED HARD -SPHERE THREE -PARAMETEREQUATION OF STATE (Ⅱ)FOR PREDICTING THERMODYNAMIC PROPERTIES OF PURE SUBSTANCES[J]. CIESC Journal, 1993, (2).
李平, 许志宏. A MODIFIED HARD -SPHERE THREE -PARAMETEREQUATION OF STATE (Ⅱ)FOR PREDICTING THERMODYNAMIC PROPERTIES OF PURE SUBSTANCES[J]. CIESC Journal, 1993, (2).DOI:
In order to extend the applicability of the MCSPT equation to other substances including ether
ester
ketone
amine
nitrile etc. The characteristic parameters of the MCSPT equation A 1
A2
A3
A4 and A5 are generalized with acentric factor. w and critical compressibility factor Zc. Saturated properties for 72 substances and the enthalpies of vaporization for 151 substances
including strongly polar componds
are predicted by the generalized MCSPT equation. The results show that of the generalized MCSPT equation is possessed of good adaptability and accuracy.