LIU Xiaojuan, HUANG Bichun, FU Mingli, et al. Performance of La0.8K0.2Mn0.95Cu0.05O3 in oxidizing model soot in atmosphere mixed with SO2[J]. CIESC Journal, 2010, (3): 704-711.
LIU Xiaojuan, HUANG Bichun, FU Mingli, et al. Performance of La0.8K0.2Mn0.95Cu0.05O3 in oxidizing model soot in atmosphere mixed with SO2[J]. CIESC Journal, 2010, (3): 704-711.DOI:
La0.8K0.2Mn0.95Cu0.05O3 perovskite-type oxide was synthesized by the complex method of citric acid
then was supported on γ-Al2O3 to obtain a series of loadings by using the impregnation method
complexing method and mixing method. Temperature programmed oxidation (TPO) was used to investigate their catalytic behavior of model soot oxidation in a feed gas containing various concentrations of SO2. The catalysts were characterized with XRD
BET
and FT-IR. XRD and BET results showed that the catalysts exhibited good structure of perovskite-type before being supported
and the specific surface area increased after being supported. TPO tests revealed that the activity of La0.8K0.2Mn0.95Cu0.05O3/γ-Al2O3 prepared by the impregnation method with 20%(mass) loading was better. La0.8K0.2Mn0.95Cu0.05O3 catalyst presented higher catalytic activity than those supported ones
i. e. La0.8K0.2Mn0.95Cu0.05O3/γ-Al2O3
however
sulfur-resistance of catalysts was improved when supported on γ-Al2O3. FT-IR spectrum confirmed that with increasing concentration of SO2
the SO2-4 species formed and accumulated on the catalyst surface would inhibit the catalytic activity.