CHEN Junhua, WANG Fei, DING Zhijie, et al. Structure and antibacterial ability of in situ silver-modified hexagonal mesoporous silica[J]. CIESC Journal, 2009, (5): 1306-1314.
CHEN Junhua, WANG Fei, DING Zhijie, et al. Structure and antibacterial ability of in situ silver-modified hexagonal mesoporous silica[J]. CIESC Journal, 2009, (5): 1306-1314.DOI:
Silver-modified hexagonal mesoporous silica (Ag-HMS) was in situ synthesized with the sol-gel method and by using [Ag(NH3)2]+ as the silver source.The structure and properties were characterized by XRD
FT-IR
TG-DTA
UV-Vis
ESEM
EDS and N2 adsorption/desorption
and the antibacterial ability was investigated.The results indicated that Ag-HMS had favorable mesoporous structure
thermal stability and absorption ability of ultraviolet radiation
the silver species were evenly distributed in the material and existed in the form of framework/non-framework.As compared with HMS
Ag-HMS changed significantly in terms of demoulding thermochemical process
pore volume
mesoporous degree of orderliness
specific surface area
and particle shape.The results of antibacterial experiments showed that Ag-HMS had strong inhibition on B.subtilis
E.coil
G.bacillus and S.aureus.Especially for B.subtilis and E.coil
at the dose of Ag-HMS up to 1.00 mg·L-1
these two bacteria were entirely killed after incubation for 12 h.