膜基复合溶液吸收CO<sub>2</sub>过程模拟

陆建刚; 王连军; 刘晓东; 孙秀云; 李健生

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膜基复合溶液吸收CO₂过程模拟

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- 膜基复合溶液吸收CO₂过程模拟
- Modeling of membrane-based absorption of CO₂ into complex solution
- 化工学报 2005年第8期页码：1439-1444
- 作者机构：
  
  南京理工大学化工学院,江苏,南京,210094
- 作者简介：
- 基金信息：
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- 网络首发：2005-08-25，
  
  纸质出版：2005-08-25
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陆建刚, 王连军, 刘晓东, 等. 膜基复合溶液吸收CO₂过程模拟[J]. 化工学报, 2005,(8):1439-1444.

LU Jiangang, WANG Lianjun, LIU Xiaodong, et al. Modeling of membrane-based absorption of CO₂ into complex solution[J]. CIESC Journal, 2005, (8): 1439-1444.
陆建刚, 王连军, 刘晓东, 等. 膜基复合溶液吸收CO₂过程模拟[J]. 化工学报, 2005,(8):1439-1444. DOI：

LU Jiangang, WANG Lianjun, LIU Xiaodong, et al. Modeling of membrane-based absorption of CO₂ into complex solution[J]. CIESC Journal, 2005, (8): 1439-1444. DOI：

摘要

建立了膜基复合溶液吸收CO2传质微分方程模型，模型中考虑了MDEA-AMP复合溶剂吸收反应交互作用和溶剂对膜孔的湿润性两种因素，模拟了这两种因素、不同气液速及不同组件对传质过程的影响，通过SEM摄片考察了溶剂对膜结构形态的影响.结果表明：交互作用和湿润性是影响传质过程不可忽略的重要因素;MDEA和AMP的增强因子对总增强因子不具有加和性;湿润使膜相阻力迅速上升，成为传质阻力的主导项;高液速时膜孔易被湿润;SEM摄片发现溶剂使膜孔增大，长时间运行疏水性膜有亲水化趋势.考虑交互因子β和湿润率η的模型，模型值与实验值符合更好.

Abstract

A model of differential equations for membrane-based absorption of CO2 into complex solutions was presented and

interaction between methyldiethanolamine (MDEA) and 2-amino-2-methyl-1-propanol (AMP) in reactions with CO2 and wetting of the solutions on membrane pores were taken into account in the model.The effects of various factors such as interaction

wetting

modules

liquid and gas velocities

on mass transfer were simulated.Additionally

the effect of the solutions on membrane configuration was analyzed by SEM images.Interaction and wetting were significant non-negligible factors in mass transfer.Overall enhancement factor of complex solution was not summation of that of MDEA and AMP.Membrane resistance rapidly increased and became dominant with partial membrane pores being wetted.Membrane pores were easily wetted at high liquid velocity.SEM images displayed that aqueous solutions of both MDEA and MDEA+AMP made pores bigger and hydrophilic.By taking account of interaction and wetting into model

simulation value was in better agreement with experimental one.

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膜基复合溶液吸收CO2过程模拟

Modeling of membrane-based absorption of CO2 into complex solution

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摘要

Abstract

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references

膜基复合溶液吸收CO₂过程模拟

Modeling of membrane-based absorption of CO₂ into complex solution