乙腈-乙醇-水-四丁基溴化铵体系中蒽和柴油的电解加氢

刘昌见; 李德宝; 鲍晓军; 杨世成; 李维彬; 胡胜; 张志华

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乙腈-乙醇-水-四丁基溴化铵体系中蒽和柴油的电解加氢

能源和环境工程 | 更新时间：2025-12-10

- 乙腈-乙醇-水-四丁基溴化铵体系中蒽和柴油的电解加氢
- Electrolytic hydrogenation of anthracene and diesel fuel in CH₃CN-EtOH-H₂O-Bu₄NBr electrolytic system
- 化工学报 2005年第2期页码：338-341
- 作者机构：
  
  1. 石油大学（北京）化工学院中国石油天然气集团公司催化重点实验室,北京,102249
  2. 中国石油天然气股份公司大庆石化公司研究院,黑龙江,大庆,163714
- 作者简介：
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- 网络首发：2005-02-25，
  
  纸质出版：2005-02-25
- 稿件说明：
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刘昌见, 李德宝, 鲍晓军, 等. 乙腈-乙醇-水-四丁基溴化铵体系中蒽和柴油的电解加氢[J]. 化工学报, 2005,(2):338-341.

LIU Changjian, LI Debao, BAO Xiaojun, et al. Electrolytic hydrogenation of anthracene and diesel fuel in CH₃CN-EtOH-H₂O-Bu₄NBr electrolytic system[J]. CIESC Journal, 2005, (2): 338-341.
刘昌见, 李德宝, 鲍晓军, 等. 乙腈-乙醇-水-四丁基溴化铵体系中蒽和柴油的电解加氢[J]. 化工学报, 2005,(2):338-341. DOI：

LIU Changjian, LI Debao, BAO Xiaojun, et al. Electrolytic hydrogenation of anthracene and diesel fuel in CH₃CN-EtOH-H₂O-Bu₄NBr electrolytic system[J]. CIESC Journal, 2005, (2): 338-341. DOI：

摘要

Abstract

Electrochemical hydrogenation of anthracene was carried out in a divided three-electrode cell with spumous Pb as cathode

Pt as anode and saturated calomel electrode as reference electrode in CH3CN-EtOH-H2O-Bu4NBr electrolytic system.The curve of current-potential was determined and the effects of solvents

water content

supporting electrolyte

anthracene content and temperature were investigated.The optimum conditions were found as potential=-1900 mV

［CH3CN］/［EtOH］＝2/1(vol)，［H2O］＝5.5 mol8226;L-1

［Bu4NBr］＝0.50 mol8226;L-1 and T=35 ℃.The yield of dihydroanthracene was 91.37% for 6 h electrolysis under these conditions.Based on the result of electrochemical hydrogenation of anthracene

electrochemical hydrogenation of Daqing FCC diesel fuel was studied with spumous Pb as cathode in CH3CN-EtOH-H2O-Bu4NBr system for 5 h electrolysis.Hydrogen content of diesel fuel increased by 1.1%

alkenes were saturated and polycyclic aromatics decreased apparently.

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