HAN Sen, YU Kailu, HE Fei, et al. PLASMA-ENHANCED PREPARATION OF HIGHLY DISPERSED Pd/Al2O3 CATALYST FOR CATALYTIC COMBUSTION OF METHANE[J]. CIESC Journal, 2003, (5): 702-703.
HAN Sen, YU Kailu, HE Fei, et al. PLASMA-ENHANCED PREPARATION OF HIGHLY DISPERSED Pd/Al2O3 CATALYST FOR CATALYTIC COMBUSTION OF METHANE[J]. CIESC Journal, 2003, (5): 702-703.DOI:
A novel Pd/Al2O3 catalyst prepared by glow discharge plasma technology is reported.The results of H2-chemisorption indicate that palladium dispersion of the plasma-prepared Pd/Al2O3 reaches 29.7%
which is about 5 times higher than Pd/Al2O3 prepared by conventional preparation.Meanwhile
the particle diameter of the plasma-prepared catalyst is 3.8 nm
but the particle diameter of the conventional catalyst is 20.4 nm.Such plasma-prepared Pd/Al2O3 catalyst shows a higher activity for catalytic combustion of methane than the conventional catalyst.Methane conversion reaches 90% at 400 ℃
but it is only near 30% for the conventional catalyst at the same temperature.