LI Li, MENG Xianghai, WANG Gang, et al. Reaction performance and product properties of catalytic pyrolysis of naphthenic-base gas oils[J]. CIESC Journal, 2010, (9): 2365-2372.
LI Li, MENG Xianghai, WANG Gang, et al. Reaction performance and product properties of catalytic pyrolysis of naphthenic-base gas oils[J]. CIESC Journal, 2010, (9): 2365-2372.DOI:
Reaction performance and product properties of catalytic pyrolysis of HGO (heavy gas oil) and LGO (light gas oil) derived from Canadian synthetic crude oil were investigated in a riser unit.The yield of total light olefins (ethylene
propylene
and butylene) showed a maximum with increasing reaction temperature and catalyst-to-oil mass ratio
decreased with increasing reaction time
and enhanced with increasing steam-to-oil mass ratio.The optimal reaction temperature
catalyst-to-oil mass ratio
reaction time and steam-to-oil mass ratio of catalytic pyrolysis of HGO were 620—640℃
16
2 s and 0.5
respectively.Under these optimal reaction conditions
the yields of ethylene
propylene and total light olefins reached 9.0%(mass)
15.8%(mass) and 32.6%(mass)
respectively.There were large amounts of aromatics in pyrolysis gasoline
diesel and heavy oil fractions.Gasoline fraction contained above 80%(mass) of aromatics which were mainly toluene and C8 aromatics.Diesel fraction contained above 60%(mass) of aromatics which were mainly single-ring and double-ring aromatics.Heavy oil fraction contained above 70%(mass) of aromatics which were mainly multi-ring aromatics.