HUANG Linyong, LIU Hong, LIU Duo, et al. Solvothermal in-situ synthesis of zinc based ZnS nanorods array and its optical properties[J]. CIESC Journal, 2010, (10): 2714-2718.
HUANG Linyong, LIU Hong, LIU Duo, et al. Solvothermal in-situ synthesis of zinc based ZnS nanorods array and its optical properties[J]. CIESC Journal, 2010, (10): 2714-2718.DOI:
ZnS nanorods array on zinc foil was prepared through a solvothermal synthesis route using zinc foil as zinc source and substrate.ZnS nanorods grew along the [001] direction which was perpendicular to the substrate.X-ray diffraction(XRD)and scanning electron microscope(SEM)were used to characterize the as-prepared nanorods array grown under different conditions.UV-Vis diffuse-reflectance spectra of the ZnS nanorods array were also performed by using Shimadzu UV-2550.The results showed well crystalline ZnS nanorods when temperature was 180℃,and reaction time was 8 h.The band-edge absorption of ZnS nanorods array was located at 347 nm,corresponding to the band gap of 3.47 eV.The chemical reaction mechanism of ZnS nanorods formed was discussed.