LUO Na, YE Zhencheng, ZHONG Weimin, et al. Dynamic simulation of primary esterification section of poly(ethylene-terephthalate)[J]. CIESC Journal, 2010, (8): 1933-1941.
LUO Na, YE Zhencheng, ZHONG Weimin, et al. Dynamic simulation of primary esterification section of poly(ethylene-terephthalate)[J]. CIESC Journal, 2010, (8): 1933-1941.DOI:
Dynamic model is the basis of dynamic optimization in chemical process.In this paper a dynamic model for esterification section of poly(ethylene-terephthalate) (PET) was developed using segment method.Different from other researches
the model considered the interaction between esterification reactor and the column.Dynamic responses of process operating condition were analyzed with basic control strategies.Simulation results show that properties of products such as carboxyl end concentration
degree of polymerization response quickly to step change of feed molar ratio
reactor temperature
pressure and liquid level.Also these step changes significantly affected the changes in gas flow of ethylene glycol and water.Control system plays a significant role in the stability of PET esterification process.