ZHANG Yi, CONG Yanqing, SUN Peide. Experiment and kinetic model for methyl orange wastewater removal by electrocoagulation[J]. CIESC Journal, 2009, (9): 2339-2345.
ZHANG Yi, CONG Yanqing, SUN Peide. Experiment and kinetic model for methyl orange wastewater removal by electrocoagulation[J]. CIESC Journal, 2009, (9): 2339-2345.DOI:
The methyl orange (MO) simulated dye wastewater was treated by electrocoagulation. The effect of operation parameters on MO decolorization and the kinetic model of chemical oxygen demand (CODCr) removal were investigated. Operation parameters
such as input voltage
electrode distance
initial MO concentration
electrolyte concentration and pH
were investigated based on the decolorization efficiency of MO. Experimental results showed that up to 97% of color decay was obtained after 10 min reaction with input voltage of 20 V
current of 0.4 A
electrode distance of 2.5 cm
treated volume of 500 ml
initial MO concentration of 500 mg·L-1
electrolyte KCl concentration of 0.5 g·L-1 and pH of 3.0. A kinetic model for CODCr reduction was established based on the coagulation and oxidation processes. The experimental data fitted well with the model curves. The parameters predicted from the kinetic model showed that the coagulation process was the main pathway for CODCr removal and the oxidation process was the next. In addition
the increase of Fe2+ in the solution decreased the CODCr removal.