The mechanism and characteristics of electrochemical oxidation of 1

4-dichlorobenzen in simulated wastewater were investigated on a platinum electrode.The cyclic voltammetric profiles showed that the oxidation peak potential and current density increased with the increase of the concentration of 1

4-dichlorobenzene

nevertheless

the oxidation potential of 1

4-dichlorobenzene in acetonitrile-aqueous solution was smaller than that in acetonitrile solution.Chronoamperometric experimental results suggested that the 1

4-dichlorobenzene degradation included both direct electro-oxidation of 1

4-dichlorobenzene by loss of electrons and indirect oxidation with anodically formed free radicals.Additionally

parachlorophenol

1

4-benzoquinone

maleic acid

oxalic acid

acetic acid

and formic acid were identified as main electro-oxidation products by ion chromatography or high performance liquid chromatography.Moreover

a yellow polymer film

which influenced the electrochemical oxidation process

was clearly identified as a rough surface after electrochemical reaction in comparison to a smooth and glossy surface of platinum electrodes without polymer film as observed from SEM image.