1. 西南石油大学油气藏地质及开发工程国家重点实验室
2. 西南石油大学化学化工学院
3. 中海油能源发展股份有限公司石化分公司
网络首发:2009-05-05,
纸质出版:2009-05-05
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唐晓东, 杨文倩, 王豪, 等. 直馏柴油绿色脱酸技术的实验研究[J]. 化工学报, 2009,(5):1204-1208.
TANG Xiaodong, YANG Wenqian, WANG Hao, et al. Experimental study on green deacidification technology of straight-run diesel[J]. CIESC Journal, 2009, (5): 1204-1208.
柴油醇氨法绿色脱酸技术具有不使用强酸强碱和实现零排放等特点,但存在氨与溶剂用量大、溶剂再生能耗高等问题。为克服醇氨法的缺点,在自制的实验装置上采用低温聚结过滤法对柴油醇氨法绿色脱酸技术进行实验研究。考察了氨用量、乙醇用量、剂油体积比、聚结过滤温度等对脱酸效果的影响以及聚结过滤材料的再生、脱酸的操作弹性和环烷酸产品的质量。研究结果表明,在最优操作条件下,直馏柴油酸度可以从62.9 mg KOH·(100 ml)-1降至4.2 mg KOH·(100 ml)-1,脱酸率高达93.3%,精制后的柴油产品质量满足工业要求[酸度X﹤7.0 mg KOH·(100 ml)-1],环烷酸粗酸值满足SH/T 0530—92的2号酸标准。该方法具有流程简单、脱酸操作温度低、氨与溶剂用量低、溶剂再生能耗低和操作弹性高等优点。
The green deacidification technology of diesel by the ammonia-alcohol method without using strong acid and strong base can achieve zero-emission.But it has some problems
such as requiring larger amounts of ammonia and solvent
and higher energy consumption of regeneration solvent.To overcome the shortcomings of the ammonia-alcohol method
this paper experimentally studied the green deacidification technology of diesel by the ammonia-alcohol method
which used low-temperature coalescence filtration in a self-made experimental device.The effects of coalescence filtration temperature
amount of ammonia
alcohol consumption
volume ratio of solvent to oil on the deacidification process
material regeneration of coalescence filtration
deacidification’s turndown ratio and the product quality of naphthenic acid were studied.The results showed that under the optimum operation condition
the acidity of straight-run diesel could decrease from 62.9 mg KOH·(100 ml)-1 to 4.2 mg KOH·(100 ml)-1
the acid removal rate was as high as 93.3%
and product recovery could reach 98.6%.After refining
the quality of diesel could meet industry requirements [acidity X<7.0 mg KOH·(100 ml)-1]
and raw acid value of naphthenic acid could meet No.2 acid standards of SH/T 0530—92.This method had the advantages of simple technological process
low operating temperature of deacidification
less ammonia and solvent consumption
low solvent regeneration energy consumption and higher turndown ratio.
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