ZHANG Keju, WANG Leming, LI Xiaohong, et al. Synthesis of superabsorbent resin of konjac glucomannan grafting acrylic acid/acrylamide[J]. CIESC Journal, 2007, (6): 1592-1597.
ZHANG Keju, WANG Leming, LI Xiaohong, et al. Synthesis of superabsorbent resin of konjac glucomannan grafting acrylic acid/acrylamide[J]. CIESC Journal, 2007, (6): 1592-1597.DOI:
A superabsorbent resin was prepared through free-radical polymerization in aqueous solution;which used konjac glucomannan(KGM);acrylic acid(AA)and acrylamide(AM)as raw materials.Graft polymerization was initiated by potassium persulfate(K2S2O8);with N;N′-methylene-bis-acrylamide(NMBA)was used as crosslinking agent .The relationships between the water absorption of the resin and the amounts of initiator;crosslinker;AA and AM as well as reaction temperature
reaction time were studied.This superabsorbent polymer was capable of absorbing distilled water up to 720 times and 0.9%NaCl solution 110 times in its saturated state at ambient temperature when the mass ratio of KGM to monomer was 1∶4;the amount of initiator was 0.35%(based on the weight of monomer);the neutralization degree of monomer was 80 %;the reaction temperature was 55~65℃;and the amount of crosslinker was 0.075%(based on the weight of monomer).Experimental results indicated that the introduction of nonionic group would be suitable for improving absorption ability and salt-resistance of the resulting hydrogels.