ZHAO Wei, LI Zengxi, ZHANG Suojiang, et al. Oxidative esterification of methacrolein to methyl methacrylate[J]. CIESC Journal, 2005, (9): 1690-1693.DOI:
Supported multi-metal catalyst was prepared by impregnation.A variety of factors such as reaction temperature
feedstock ratio
alkali concentration
catalyst concentration and antipolymerizer concentration were systematically investigated in terms of their effects on the oxidative esterification reaction for methyl methacrylate production from methacrolein.The experimental results showed that under the condition of temperature 333 K,methanol/methacrolein ratio 97∶1(molar ratio),NaOH concentration 0.001 g8226;ml-1 and catalyst concentration 0.02 g8226;ml-1
methacrolein conversion and methyl methacrylate selectivity were about 100% and 71.4% respectively