2-戊基蒽醌在TMB/TOP中溶解度的测定与关联

刘国柱; 程淑颖; 王莅; 米镇涛; 常贺英

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2-戊基蒽醌在TMB/TOP中溶解度的测定与关联

热力学 | 更新时间：2025-12-10

- 2-戊基蒽醌在TMB/TOP中溶解度的测定与关联
- MEASUREMENT AND CORRELATION OF SOLUBILITY OF 2-AMYLANTHRAQUINONE IN TMB / TOP SOLUTIONS
- 化工学报 2004年第4期页码：640-642
- 作者机构：
  
  1. 天津大学化工学院
  2. 化学工程联合国家重点实验室,天津,300072
- 作者简介：
- 基金信息：
- DOI：
  中图分类号：
- 网络首发：2004-04-25，
  
  纸质出版：2004-04-25
- 稿件说明：
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刘国柱, 程淑颖, 王莅, 等. 2-戊基蒽醌在TMB/TOP中溶解度的测定与关联[J]. 化工学报, 2004,(4):640-642.

LIU Guozhu, CHENG Shuying, WANG Li, et al. MEASUREMENT AND CORRELATION OF SOLUBILITY OF 2-AMYLANTHRAQUINONE IN TMB / TOP SOLUTIONS[J]. CIESC Journal, 2004, (4): 640-642.
刘国柱, 程淑颖, 王莅, 等. 2-戊基蒽醌在TMB/TOP中溶解度的测定与关联[J]. 化工学报, 2004,(4):640-642. DOI：

LIU Guozhu, CHENG Shuying, WANG Li, et al. MEASUREMENT AND CORRELATION OF SOLUBILITY OF 2-AMYLANTHRAQUINONE IN TMB / TOP SOLUTIONS[J]. CIESC Journal, 2004, (4): 640-642. DOI：

摘要

Abstract

2-Amylanthraquinone (AAQ) is a novel

effective working carrier and a potential substitute of 2-ethylanthraquinone (EAQ) in hydrogen peroxide production process.In order to obtain the basic data for the process development

the equilibria method was used to experimentally measure the solubility of AAQ in the mixed organic solvents of trimethylbenzen(TMB) and trioctyl phosphate(TOP) with different volume ratios

at 298.15—323.15 K. It was found that the solubility of AAQ was ca. 3 times greater than EAQ at the same conditions. Finally

experimental data were correlated by the modified λ-h equation

in which a factor of the solvent composition was added.The results showed that the modified λ-h equation can be used to predict the solubility of AAQ in TMB/TOP system with an average relative deviation (ARD) of 5%.

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