丙烯腈/N-乙烯基吡咯烷酮共聚物结构和热解反应表观活化能

陈厚; 王成国; 蔡华甦; 崔传生

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丙烯腈/N-乙烯基吡咯烷酮共聚物结构和热解反应表观活化能

催化、动力学与反应器 | 更新时间：2025-12-10

- 丙烯腈/N-乙烯基吡咯烷酮共聚物结构和热解反应表观活化能
- APPARENT ACTIVATION ENERGY OF PYROLYSIS REACTION OF COPOLYMERS OF ACRYLONITRILE AND N-VINYLPYRROLIDONE
- 化工学报 2003年第1期页码：124-127
- 作者机构：
  
  山东大学材料科学与工程学院
- 作者简介：
- 基金信息：
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- 网络首发：2003-01-25，
  
  纸质出版：2003-01-25
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陈厚, 王成国, 蔡华甦, 等. 丙烯腈/N-乙烯基吡咯烷酮共聚物结构和热解反应表观活化能[J]. 化工学报, 2003,(1):124-127.

CHEN Hou, WANG Chengguo, CAI Huasu, et al. APPARENT ACTIVATION ENERGY OF PYROLYSIS REACTION OF COPOLYMERS OF ACRYLONITRILE AND N-VINYLPYRROLIDONE[J]. CIESC Journal, 2003, (1): 124-127.
陈厚, 王成国, 蔡华甦, 等. 丙烯腈/N-乙烯基吡咯烷酮共聚物结构和热解反应表观活化能[J]. 化工学报, 2003,(1):124-127. DOI：

CHEN Hou, WANG Chengguo, CAI Huasu, et al. APPARENT ACTIVATION ENERGY OF PYROLYSIS REACTION OF COPOLYMERS OF ACRYLONITRILE AND N-VINYLPYRROLIDONE[J]. CIESC Journal, 2003, (1): 124-127. DOI：

摘要

Abstract

The pyrolysis reaction of acrylonitrile(AN)/N-vinylpyrrolidone(N-VP) copolymer in air was studied with DSC. The apparent activation energy of pyrolysis reaction of copolymer was calculated by the Kissinger method. The effect of different copolymerization conditions on the apparent activation energy of copolymer was discussed. It was found that with an increase of DMSO concentration in mixture solvent，the degradation apparent activation energy rose rapidly. When the weight ratio of N-VP/AN was less than 5/95

the apparent activation energy of degradation reduced quickly with the comononer N-VP concentration rising

and when the ratio was more than 5/95

the apparent activation energy became almost constant. When the copolymerization temperature rose

the apparent activation energy also increased.

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