The method of thermal frontal polymerization (TFP) was used to cure the selected alicyclic epoxy resin. The effect of the factors
including amount of curing agent
preheating temperature and tilt angle of reactor
on frontal velocity and frontal temperature was investigated. The structure and thermal properties of the cured products were characterized with FTIR
DSC and TG analysis. The results showed that both frontal velocity Vf and maximum frontal temperature Tmax increased with increasing amount of curing agent or preheating temperature
while initiation time and the time needed to reach the highest frontal temperature decreased. When the reactor tilted
the heading direction of the descending front would drift
and frontal velocity would tend to slow down. The analysis of FTIR spectrum indicated that the products obtained by the TFP method exhibited similar infrared absorption as compared to that of the products prepared by the traditional thermal curing method. DSC and TG results revealed that the products obtained by the TFP method had higher glass transition temperature and better thermal stability.
Properties of biphenyl A epoxy resin modified by choromethyl polyhedral silsesquioxane
Study on pyrolysis characteristics of cellulose-enhanced epoxy resin composites
Preparation and performance evaluation of magnolol-based epoxy resin anti-corrosion coatings
Synthesis and curing kinetic analysis of eugenol-based siloxane epoxy resin
Synthesis and curing kinetics of terephthalaldehyde phenolic resin
Related Author
TAN Jun
WANG Huajin
SHA Baoxiang
WEI Xiaoyan
YU Qiang
LIU Shijun
ZHENG Anqing
CHEN Xiaoli
Related Institution
School of Materials Science and Engineering, Changzhou University
School of Materials and Textile Engineering, Jiaxing University
School of Biological and Chemical Engineering, Jiaxing University
School of Energy Science and Engineering, University of Science and Technology of China
CAS Key Laboratory of Renewable Energy, Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences