Advances in catalytic oxidations catalyzed by carbon nanomaterials in liquid-phase

CAO Yonghai; LI Bo; YU Hao; PENG Feng; WANG Hongjuan

doi:10.3969/j.issn.0438-1157.2014.07.024

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Advances in catalytic oxidations catalyzed by carbon nanomaterials in liquid-phase

更新时间：2025-12-10

- Advances in catalytic oxidations catalyzed by carbon nanomaterials in liquid-phase
- CIESC Journal Issue 7, Pages: 2645-2656(2014)
- 作者机构：
  
  华南理工大学化学与化工学院,广东,广州,510640
- 作者简介：
- 基金信息：
- DOI：10.3969/j.issn.0438-1157.2014.07.024
  CLC： Q028.8
- Online First：05 July 2014，
  
  Published：05 July 2014
- 稿件说明：
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CAO Yonghai, LI Bo, YU Hao, et al. Advances in catalytic oxidations catalyzed by carbon nanomaterials in liquid-phase[J]. CIESC Journal, 2014, (7): 2645-2656.
DOI：

CAO Yonghai, LI Bo, YU Hao, et al. Advances in catalytic oxidations catalyzed by carbon nanomaterials in liquid-phase[J]. CIESC Journal, 2014, (7): 2645-2656. DOI： 10.3969/j.issn.0438-1157.2014.07.024.

摘要

纳米碳材料是广受关注的高性能材料，其作为无金属催化剂的应用近年来受到了广泛关注。综述了碳材料在不同氧化剂（O2、H2O2、叔丁基过氧化氢、氧化石墨等）的作用下选择性催化氧化烃类、醇类、酮类、胺类等制备有机化学品和氧化降解有机污染物反应过程，着重阐述这些液相氧化反应体系的机理以及碳材料在其中所起的作用。

Abstract

Recently emerged liquid-phase oxidation processes catalyzed by carbon nanomaterials as metal-free

low-cost catalysts

either for manufacture of chemicals or for elimination of organic pollutants are reviewed. Oxidations of hydrocarbon

alcohol

ketone

amine

etc. are involved

categorized by the oxidant used

such as O2

H2O2

tert-butyl hydroperoxide

graphite oxide. The reaction processes and catalytic mechanisms are discussed to elucidate the role of carbon nanomaterials as a new class of catalyst.

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