HAO Han, FENG Jianguo, MA Chao, et al. Influence of double comb-shaped copolymer on dispersion stability of imidacloprid suspension[J]. CIESC Journal, 2014, (3): 1126-1134.
DOI:
HAO Han, FENG Jianguo, MA Chao, et al. Influence of double comb-shaped copolymer on dispersion stability of imidacloprid suspension[J]. CIESC Journal, 2014, (3): 1126-1134.DOI: 10.3969/j.issn.0438-1157.2014.03.050.
Influence of double comb-shaped copolymer on dispersion stability of imidacloprid suspension
the influence of a double comb-shaped copolymer (AgrilanTM 752) on dispersion stability of imidacloprid suspension was studied with FTIR
SEM
XPS
zeta potential and particle size tests. AgrilanTM 752
which contained carboxyl groups
ester groups and poly-oxyethylene chain
combined with imidacloprid by hydrogen bond
van der Waals force and hydrophobic interaction
and dispersed imidacloprid particles in suspensions effectively. The experimental data indicated that thickness of AgrilanTM 752 adsorbed layers
zeta potential and dispersion stability of suspension reached maximum values when its content was 3%(mass)
i.e.
the optimum AgrilanTM 752 content under this experimental conditions was 3%(mass). Thickness of AgrilanTM 752 adsorbed layers decreased at initial pH > 6
zeta potential had a maximum value at initial pH = 10. On the other hand
dispersion stability was good at initial pH from 2 to 10
and became worse with increasing initial pH value. Moreover
experimental results suggested that electrolyte ions
such as Na+
Mg2+ and Ca2+ reduced thickness of AgrilanTM 752 adsorbed layers and zeta potential
and decreased the dispersion stability of imidacloprid suspension. Moreover
the ability of decreasing dispersion stability of imidacloprid suspension was Ca2+ > Mg2+ > Na+ at the same concentration.
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