Preparation of polyethylene/MMT/MWCNTs nanocomposite by in-situ polymerization

ZHANG Letian; QIAO Xinfeng; DAI Shiwei; ZHANG Zhenfei; YE Xiaofeng

doi:10.3969/j.issn.0438-1157.2013.10.051

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Preparation of polyethylene/MMT/MWCNTs nanocomposite by in-situ polymerization

更新时间：2025-12-10

- Preparation of polyethylene/MMT/MWCNTs nanocomposite by in-situ polymerization
- CIESC Journal Issue 10, Pages: 3865-3870(2013)
- 作者机构：
  
  上海化工研究院有机化工研究所, 上海市聚烯烃催化技术重点实验室,上海,200062
- 作者简介：
- 基金信息：
- DOI：10.3969/j.issn.0438-1157.2013.10.051
  CLC： Q325.14
- Online First：05 October 2013，
  
  Published：05 October 2013
- 稿件说明：
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ZHANG Letian, QIAO Xinfeng, DAI Shiwei, et al. Preparation of polyethylene/MMT/MWCNTs nanocomposite by in-situ polymerization[J]. CIESC Journal, 2013, (10): 3865-3870.
DOI：

ZHANG Letian, QIAO Xinfeng, DAI Shiwei, et al. Preparation of polyethylene/MMT/MWCNTs nanocomposite by in-situ polymerization[J]. CIESC Journal, 2013, (10): 3865-3870. DOI： 10.3969/j.issn.0438-1157.2013.10.051.

摘要

Abstract

Heterogeneous Z-N catalysts were prepared by loading TiCl4 on a mixture of modified nanoclays and functionalized carbon nanotubes as effective composite nanofillers in magnesium chloride.The polyethylene nanocomposites were produced via in-situ polymerization.The properties of nanocomposites were studied by controlling the content of montmorillonite(MMT)

multi-walled carbon nanotubes(MWCNTs)in MgCl2.Highly active polymerization catalyst with the nanofillers containing MMT

modified MWCNTs and MgCl2 could be obtained.Mechanical properties of polyethylene containing composite nanofillers were better than those of polyethylene resin containing only one kind of nanofiller.WAXD analysis of the composites indicated that composite nanofillers of low content were uniformly dispersed in PE matrix and played an effective enhancement effect.

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