GAO Yan, LUAN Tao, PENG Jiwei, et al. DeNOx performance of SCR catalyst for exhaust gas from coal-fired power plant[J]. CIESC Journal, 2013, (7): 2611-2618. DOI: 10.3969/j.issn.0438-1157.2013.07.041.
DOI:
GAO Yan, LUAN Tao, PENG Jiwei, et al. DeNOx performance of SCR catalyst for exhaust gas from coal-fired power plant[J]. CIESC Journal, 2013, (7): 2611-2618. DOI: 10.3969/j.issn.0438-1157.2013.07.041.DOI:
DeNOx performance of SCR catalyst for exhaust gas from coal-fired power plant
A honeycomb SCR catalyst of V2O5/TiO2 with WO3 and MoO3 was prepared and its deNOx performance was investigated in a pilot plant test using flue gas of a coal-fired power plant.The results show that the larger catalyst volume is
the higher deNOx efficiency
and SO2 oxidation increases too
but increase ratio becomes smaller.When deNOx efficiency is above 80%
the outlet NOx concentration met the emission standards
and the efficiency improvement is not significant by further enlarging catalyst volume which led to higher construct cost.In order to obtain the best ratio of deNOx efficiency to catalyst volume and avoid resources waste for single requirement of higher deNOx efficiency
SCR catalyst volume should be adjusted for different boiler types
according to flue gas component of coal-fired power plant and national emission standards.The deNOx efficiency reduces with soot increase deposited
and drops about 9.4% within 4 h of soot depositing.The outlet NOx concentration can be at 198 mg·m-3 after 8 h of soot depositing.At 0.031 kg·m-3 of fly ash concentration
the soot deposited needed to be blown each 6 h to obtain a satisfied deNOx efficiency (>80%).When run time prolongs
the deNOx efficiency falls sharply first
and then reaches a relative stable level.Within 48—168 h
the deNOx efficiency and SO2 oxidation decline less than 1% and 0.1%
respectively.After continuous run for 3 months (2160 h)
the NOx concentration at outlet of SCR tower is 196 mg·m-3.The deNOx efficiency declines at a rate of 1% per 700 h for continuous 12 month run.