LU Bona, CHENG Congli, LU Weimin, et al. Numerical simulation of reaction process in MIP riser based on multi-scale model[J]. CIESC Journal, 2013, (6): 1983-1992.
DOI:
LU Bona, CHENG Congli, LU Weimin, et al. Numerical simulation of reaction process in MIP riser based on multi-scale model[J]. CIESC Journal, 2013, (6): 1983-1992.DOI: 10.3969/j.issn.0438-1157.2013.06.012.
Numerical simulation of reaction process in MIP riser based on multi-scale model
MIP (maximizing iso-paraffins process) process utilizes the technique of linking two reaction zones in series
and hence effectively improves gasoline quality.Cold simulation of MIP reactors can reveal the flow structures in the second reaction zone and also the effects of geometrical structures
but cannot provide the changes in hydrodynamics resulting from catalytic cracking reactions.To capture these changes
this work aimed at carrying out three-dimensional simulation of the MIP reactor by considering the reactions.The simulation was based on the two-fluid model and 12-lump kinetic model.The inter-phase momentum transfer and heat transfer models took into account the effects of multi-scale flow structures
and were compared with the traditional models based on homogeneous state.The simulation found that the multi-scale models could reasonably predict the flow structures and solids volume fraction in the second reaction zone as well as the temperature profiles
compared to the traditional model.For predicting product yields
both models showed similar results.They had good predictions in slurry and diesel
but fail to predict LPG and dry gas.The above finding implied that the effects of multi-scale structures should not only be considered in the momentum transfer and heat transfer models
but also be taken into account in the lumped kinetic model.