CHEN Bo, QUAN Xuejun, CHENG Zhiliang, et al. Electrochemical oxidation of biologically treated leachate from municipal solid waste incineration plant[J]. CIESC Journal, 2013, (4): 1396-1402.
DOI:
CHEN Bo, QUAN Xuejun, CHENG Zhiliang, et al. Electrochemical oxidation of biologically treated leachate from municipal solid waste incineration plant[J]. CIESC Journal, 2013, (4): 1396-1402.DOI: 10.3969/j.issn.0438-1157.2013.04.037.
Electrochemical oxidation of biologically treated leachate from municipal solid waste incineration plant
Incineration is an effective technology for municipal solid waste (MSW) disposal.However
the MSW leachate after bio-treatment still contains recalcitrant organic compounds
higher concentration of chloride ions and biogenic colloids.Their electrochemical oxidation was conducted in a newly designed filter-press electrochemical reactor.In the electrochemical oxidation process
NH3-N could be easily removed by means of electro-generated chlorine/hypochlorite.The effects of major process parameters on the removal of organic pollutants were investigated systematically.Under experimental conditions
the optimum operation parameters are current density 65.35 mA穋m-2
flow velocity 2.72 cm穝-1 in electrode gap
initial chloride ion concentration 5000 mg稬-1.The COD in the leachate could be reduced below 100 mg稬-1 after 1 h of treatment.The kinetics and mechanism of COD removal were investigated by simultaneously monitoring the COD change and chlorine/hypochlorite production.The kinetics exhibits a two-stage kinetic model and the decrease of electro-generated chlorine/hypochlorite production is the major factor for slowing down of COD removal rate in the second stage.50% of reduction in electrode gap can result in saving more than 25% of energy consumption.A compact multi-channel bipolar structure should be taken in the design of industrial electrochemical reactors for wastewater treatment.