Controllable preparation of complex polymer chains and novel materials

罗英武

doi:10.3969/j.issn.0438-1157.2013.02.004

您当前的位置：

首页 >

文章列表页 >

Controllable preparation of complex polymer chains and novel materials

更新时间：2025-12-10

- Controllable preparation of complex polymer chains and novel materials
- CIESC Journal Issue 2, Pages: 415-426(2013)
- 作者机构：
  
  浙江大学化学工程与生物工程学系,化学工程联合国家重点实验室,浙江,杭州,310027
- 作者简介：
- 基金信息：
- DOI：10.3969/j.issn.0438-1157.2013.02.004
  CLC： Q31
- Online First：05 February 2013，
  
  Published：05 February 2013
- 稿件说明：
移动端阅览
罗英武. Controllable preparation of complex polymer chains and novel materials[J]. CIESC Journal, 2013, (2): 415-426.
DOI：

罗英武. Controllable preparation of complex polymer chains and novel materials[J]. CIESC Journal, 2013, (2): 415-426. DOI： 10.3969/j.issn.0438-1157.2013.02.004.

摘要

自由基聚合与配位聚合的产物通常为宽分子量分布的均聚物或无规共聚物。近二十年来

活性/可控自由基聚合、活性/可控配位聚合、链穿梭聚合的研究取得突破。这些方法使得几乎所有的乙烯基单体

特别是廉价易得的单体

都可用作原料来制备原来无法制备得到的两嵌段、多嵌段共聚物、梯度共聚物等更为复杂聚合链结构。合理设计这些复杂的链结构

有望得到高性能、高附加值合成材料。介绍了这些新型聚合原理的机理、新进展

讨论了它们潜在的应用前景。

Abstract

The product from free radical and coordination polymerization generally are homopolymer or random copolymer with broad molecular weight distribution.In the past two decades

the breakthroughs in controlled/living radical and coordination polymerization and shuttling polymerization make it possible to use almost all vinyl monomers

particularly those cheap monomers

to produce more complex chain structures like di-

tri-block copolymer and gradient copolymers.With rational design

these copolymers might be high performance and high added value synthetic materials.The mechanisms and the up-to-date progress of these polymerization methods were introduced

and their possible applications were discussed.

关键词

Keywords

references

Views

518

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Low modulus, high elasticity and high peel adhesion acrylate pressure sensitive adhesives

Synthesis process optimization and degradation properties of PLA/PBAu block copolymer

Preparation of poly(styrene-b-butyl acrylate-b-styrene) copolymers by single electron transfer-degenerative chain transfer living free radical miniemulsion polymerization

Synthesis and characterization of block copolymers of poly(silane arylacetylene) and poly(siloxane arylacetylene)

Preparation of hierarchical porous carbons from vinylidene chloride-based block copolymers

Related Author

ZHANG Ao

LUO Yingwu

CUI Lingna

LIU Yuejun

XU Jinchao

BAO Yongzhong

DU Lei

HUANG Farong

Related Institution

State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University

Key Laboratory of Advanced Packaging Materials and Technology of Hunan Province, Hunan University of Technology

State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University

Key Laboratory for Specially Functional Polymeric Materials and Related Technology of Ministry of Education (East China University of Science and Technology)

State Key Laboratory of Chemical Engineering, Department of Chemical and Biological Engineering, Zhejiang University

⁰