Preparation of a novel crown ether functionalized ionic liquid［A（benzo15C5）HIM］［(CF3SO2）2N］

王江

doi:10.3969/j.issn.0438-1157.2011.z2.030

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Preparation of a novel crown ether functionalized ionic liquid［A（benzo15C5）HIM］［(CF₃SO₂）₂N］

更新时间：2025-12-10

- Preparation of a novel crown ether functionalized ionic liquid［A（benzo15C5）HIM］［(CF₃SO₂）₂N］
- CIESC Journal Issue S2, Pages: 165-168(2011)
- 作者机构：
  
  华中农业大学理学院
- 作者简介：
- 基金信息：
- DOI：10.3969/j.issn.0438-1157.2011.z2.030
  CLC：
- Online First：20 December 2011，
  
  Published：20 December 2011
- 稿件说明：
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王江. Preparation of a novel crown ether functionalized ionic liquid［A（benzo15C5）HIM］［(CF₃SO₂）₂N］[J]. CIESC Journal, 2011, (S2): 165-168. DOI: 10.3969/j.issn.0438-1157.2011.z2.030.
DOI：

王江. Preparation of a novel crown ether functionalized ionic liquid［A（benzo15C5）HIM］［(CF₃SO₂）₂N］[J]. CIESC Journal, 2011, (S2): 165-168. DOI: 10.3969/j.issn.0438-1157.2011.z2.030. DOI：

摘要

通过Williamson反应、Friedel-Crafts酰基化等反应合成了新型冠醚功能化离子液体1-烯丙基-3-（6′-氧代苯并-15-冠-5-己基）咪唑双三氟甲磺酰亚胺（［A（benzo15C5）HIM］［（CF3SO2）2N］），并以IR、1H NMR对其结构进行了表征。初步探讨了双酚A（BPA）在多壁碳纳米管-离子液体（MWCNTs-IL）修饰玻碳电极上的电化学行为。

Abstract

A novel crown ether functionalized ionic liquid 1-allyl-3-（6′-oxo-benzo-15-crown-5 hexyl）imidazolium bis（trifluoromethanesulfonyl）imide （［A（benzo15C5）HIM］［（CF3SO2）2N］was synthesized by Williamson reaction

Friedel-Crafts acylation of benzene reaction etc，its structures were characterized by IR，1H NMR

and the behavior of BPA in which MWCNTs-IL modified glassy carbon electrode was detected.

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