Removal of Tl from wastewater by nickel ferrite-based hydrothermal carbon coupled with hypochlorite oxidation

LIN Mao; LI Huosheng; ZHANG Gaosheng; ZHANG Ping; LONG Jianyou; XIAO Tangfu; ZHANG Hongguo; XIONG Jingfang; CHEN Yongheng

doi:10.11949/j.issn.0438-1157.20181453

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Removal of Tl from wastewater by nickel ferrite-based hydrothermal carbon coupled with hypochlorite oxidation

Energy and environmental engineering | 更新时间：2026-07-24

- Removal of Tl from wastewater by nickel ferrite-based hydrothermal carbon coupled with hypochlorite oxidation
- CIESC Journal Vol. 70, Issue 4, Pages: 1591-1604(2019)
- 作者机构：
  
  1. 广州大学化学化工学院，珠江三角洲水质安全与保护教育部重点实验室，广东广州 510006
  2. 广州大学大湾区环境研究院，广东广州 510006
  3. 广州大学环境科学与工程学院，广东广州 510006
  4. 广州大学-林雪平大学城市可持续发展研究中心，广东广州 510006
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20181453
  CLC： TQ 085⁺.41
- Received：05 December 2018，
  
  Revised：2019-01-24，
  
  Online First：15 June 2020，
  
  Published：12 April 2019
- 稿件说明：
移动端阅览
林茂, 李伙生, 张高生, 张平, 龙建友, 肖唐付, 张鸿郭, 熊静芳, 陈永亨. 铁酸镍基水热炭协同次氯酸根氧化去除废水中铊[J]. 化工学报, 2019, 70(4): 1591-1604

LIN Mao, LI Huosheng, ZHANG Gaosheng, ZHANG Ping, LONG Jianyou, XIAO Tangfu, ZHANG Hongguo, XIONG Jingfang, CHEN Yongheng. Removal of Tl from wastewater by nickel ferrite-based hydrothermal carbon coupled with hypochlorite oxidation[J]. CIESC Journal, 2019, 70(4): 1591-1604
林茂, 李伙生, 张高生, 张平, 龙建友, 肖唐付, 张鸿郭, 熊静芳, 陈永亨. 铁酸镍基水热炭协同次氯酸根氧化去除废水中铊[J]. 化工学报, 2019, 70(4): 1591-1604 DOI： 10.11949/j.issn.0438-1157.20181453.

LIN Mao, LI Huosheng, ZHANG Gaosheng, ZHANG Ping, LONG Jianyou, XIAO Tangfu, ZHANG Hongguo, XIONG Jingfang, CHEN Yongheng. Removal of Tl from wastewater by nickel ferrite-based hydrothermal carbon coupled with hypochlorite oxidation[J]. CIESC Journal, 2019, 70(4): 1591-1604 DOI： 10.11949/j.issn.0438-1157.20181453.

摘要

以铁酸镍和葡萄糖为原料构建炭包裹的磁性水热炭（NiFe

@C）作为可重复利用的高效吸附剂，并催化次氯酸根协同氧化以去除废水中的铊。考察了初始pH、混凝pH、反应温度、共存物和氧化剂投加量等因素对除铊的影响，结合X射线粉末衍射仪（XRD）、X射线光电子能谱（XPS）和电子自旋共振光谱仪（ESR）等表征手段探究了其除铊机理。在铊初始浓度20 mg/L、初始pH 10、吸附剂投加量0.5 g/L、次氯酸钠投量10 mmol/L时，铊去除率达到99%以上。Ca

、Mg

、EDTA、DPTA抑制除铊。吸附过程更适合拟一级动力学模型，等温吸附更适用于Langmuir和Temkin方程描述，最大铊吸附量达989 mg/g。NiFe

@C对Tl(I)的去除机理主要为氧化沉淀和表面羟基络合。材料再生实验表明NiFe

@C有很好的脱附与再生能力。本研究为废水除铊提供了一定的理论和技术参考依据。

Abstract

In this study

carbon-coated magnetic hydrothermal carbon (NiFe

@C) was constructed from nickel ferrite and gl

ucose as a reusable high-efficiency adsorbent

and the hypochlorite was catalyzed by oxidation to remove strontium from wastewater. The effects of initial pH

coagulation pH

reaction temperature

co-existing substance and hypochlorite dosage on thallium removal were examined

and mechanism on thallium removal was investigated by X-ray powder diffractometry (XRD)

X-ray photoelectron spectroscopy (XPS) and electron spin resonance spectroscopy (ESR). When the initial concentration of thallium was 20 mg/L

the initial pH was 10

the adsorbent dosage was 0.5 g/L

and the sodium hypochlorite dosage was 10 mmol/L

the thallium removal efficiency reached more than 99%. Ca

EDTA

and DPTA can inhibit thallium removal. The adsorption process is more suitable for the pseudo-first order kinetic model

and isothermal adsorption is more suitable for the description of Langmuir and Temkin equation. The saturated adsorption capacity is high up to 989 mg/g. The removal mechanism of Tl(I) by NiFe

@C was mainly surface hydroxyl complexation and oxidation precipitation. Material regeneration experiments show that NiFe

@C has a good ability of desorption and regeneration. This study provides a theoretical and technical reference for thallium removal in wastewater.

关键词

Keywords

references

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