Microwave synthesis and properties of dioctadecyl tetrahydroxyethyl dibromopropane diammonium

Siyu PENG; Cheng ZHENG; Taoyan MAO; Yuan WEI; Huafeng SONG

doi:10.11949/j.issn.0438-1157.20181393

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Microwave synthesis and properties of dioctadecyl tetrahydroxyethyl dibromopropane diammonium

更新时间：2020-06-24

- Microwave synthesis and properties of dioctadecyl tetrahydroxyethyl dibromopropane diammonium
- CIESC Journal Issue S1, Pages: 202-210(2019)
- 作者机构：
  
  1.广州大学精细化工研究所，广东广州 510006
  2.广州科技职业技术学院，广东广州 510550
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20181393
  CLC： TQ 423.99
- Received：21 November 2018，
  
  Revised：2018-11-26，
- 稿件说明：
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彭思玉, 郑成, 毛桃嫣, 魏渊, 宋华峰. 双十八烷基四羟乙基二溴丙二铵的微波合成及其性能研究[J]. 化工学报, 2019, 70(S1): 202-210

PENG Siyu, ZHENG Cheng, MAO Taoyan, WEI Yuan, SONG Huafeng. Microwave synthesis and properties of dioctadecyl tetrahydroxyethyl dibromopropane diammonium[J]. CIESC Journal, 2019, 70(S1): 202-210
彭思玉, 郑成, 毛桃嫣, 魏渊, 宋华峰. 双十八烷基四羟乙基二溴丙二铵的微波合成及其性能研究[J]. 化工学报, 2019, 70(S1): 202-210 DOI： 10.11949/j.issn.0438-1157.20181393.

PENG Siyu, ZHENG Cheng, MAO Taoyan, WEI Yuan, SONG Huafeng. Microwave synthesis and properties of dioctadecyl tetrahydroxyethyl dibromopropane diammonium[J]. CIESC Journal, 2019, 70(S1): 202-210 DOI： 10.11949/j.issn.0438-1157.20181393.

摘要

以十八烷基二乙醇胺、1

3-二溴丙烷为主要原料，在微波高压条件下进行季铵化反应合成了一种双子表面活性剂双十八烷基四羟乙基二溴丙二铵（DTDD），通过红外光谱（IR）和核磁共振（

H NMR）对DTDD进行了表征，并用液相色谱-质谱联用（LC-MS）测定了其纯度。通过单因素、正交实验得到了微波法合成目标产物的最佳合成条件为：设置微波功率为900 W，反应时间8 h，反应温度为140℃，产品收率达92%以上。与传统加热法对比

使用微波合成法反应速率大大提高。性能测试结果表明：对比单链季铵盐（OMDAB），目标产物DTDD具有良好的表面性能，其临界胶束浓度为0.087 g/L，相应的表面张力

(CMC)

为31.09 mN/m。

Abstract

A gemini surfactant called dioctadecyl tetrahydroxyethyl dibromopropane diammonium (DTDD) was synthesized

via

quaternization reaction under the condition of microwave and high pressure using octadecyl diethanolamine and 1

3-dibromopropane as the main raw materials. The target compound was characterized by IR and

H NMR

and its purity was determined by HPLC-ELSD. By analysing the single-factor and orthogonal array design experiments

the optimal synthesis conditions for the synthesis of DTDD by microwave method were determined as follows: microwave power was set to 900W

reaction time was 8h and reaction temperature was 140°C

reaching a yeild of 92%. Compared with the traditional heating method

the reaction rate using microwave synthesis was greatly increased. The critical micelle concentration (CMC)

surface tension

Kraft point

and foam properties of the product and the traditional surfactant octadecylmethyldihydroxyethyl ammonium bromide (OMDAB) were determined. The performance test results showed that compared with OMDAB

the target product had good surface properties with the critical micelle concentration of 0.087 g/L and the corresponding surface tension

(CMC)

of 31.09 mN/m.

关键词

Keywords

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