Preparation and lithium storage properties of flexible self-standing PDDA-Si/G nanocomposite film

Yating ZHANG; Kaibo ZHANG; Kaili JIA; Xinfu HE; Guoyang LIU; Wei WANG; Yongling ZHANG; Jieshan QIU

doi:10.11949/j.issn.0438-1157.20181287

您当前的位置：

首页 >

文章列表页 >

Preparation and lithium storage properties of flexible self-standing PDDA-Si/G nanocomposite film

Material science and engineering\, nanotechnology | 更新时间：2026-07-24

- Preparation and lithium storage properties of flexible self-standing PDDA-Si/G nanocomposite film
- CIESC Journal Vol. 70, Issue 3, Pages: 1144-1151(2019)
- 作者机构：
  
  1.西安科技大学化学与化工学院，陕西西安 710054
  2.国土资源部煤炭资源勘查与综合利用重点实验室，陕西西安 710021
  3.大连理工大学化工学院，辽宁大连 116024
  4.北京化工大学化学工程学院，北京 100029
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20181287
  CLC： TM 912.9
- Received：02 November 2018，
  
  Revised：2018-12-24，
  
  Online First：24 July 2026，
  
  Published：05 March 2019
- 稿件说明：
移动端阅览
张亚婷, 张凯博, 贾凯丽, 贺新福, 刘国阳, 王伟, 张永玲, 邱介山. 柔性自支撑PDDA-Si/G纳米复合薄膜的制备及储锂性能[J]. 化工学报, 2019, 70(3): 1144-1151

ZHANG Yating, ZHANG Kaibo, JIA Kaili, HE Xinfu, LIU Guoyang, WANG Wei, ZHANG Yongling, QIU Jieshan. Preparation and lithium storage properties of flexible self-standing PDDA-Si/G nanocomposite film[J]. CIESC Journal, 2019, 70(3): 1144-1151
张亚婷, 张凯博, 贾凯丽, 贺新福, 刘国阳, 王伟, 张永玲, 邱介山. 柔性自支撑PDDA-Si/G纳米复合薄膜的制备及储锂性能[J]. 化工学报, 2019, 70(3): 1144-1151 DOI： 10.11949/j.issn.0438-1157.20181287.

ZHANG Yating, ZHANG Kaibo, JIA Kaili, HE Xinfu, LIU Guoyang, WANG Wei, ZHANG Yongling, QIU Jieshan. Preparation and lithium storage properties of flexible self-standing PDDA-Si/G nanocomposite film[J]. CIESC Journal, 2019, 70(3): 1144-1151 DOI： 10.11949/j.issn.0438-1157.20181287.

摘要

通过静电自组装技术成功制备得到柔性自支撑聚二烯二甲基氯化铵-Si/石墨烯(PDDA-Si/G)纳米复合薄膜。该复合薄膜无添加黏结剂及导电炭黑且仍能保持电极结构的完整性，其中石墨烯提供完整的导电网络和机械韧性。电化学测试结果表明，当电流密度为0.2 A/g，复合材料的比容量可达1439.9 (mA·h)/g，库仑效率保持98%以上。且在高电流密度(2 A/g)下，复合材料的比容量仍可维持在499.9 (mA·h)/g，远高于商品化纯Si电极的电化学性能。

Abstract

Silicon is an active electrode material for future commercial lithium-ion batteries with extremely high theoretical specific capacity (4200 (mA·h)/g). However

the large volume change of silicon over charge-discharge cycles weakens its competitiveness in the capacity and cycle life. A flexible self-supporting polydiene dimethylammonium chloride-Si/graphene (PDDA-Si/G) nanocomposite film was successfully prepared by electrostatic self-assembly technique. The composite film can maintain the integrity of electrode structure without adding binder and conductive carbon black. Graphene provides complete conductive network and mechanical toughness. The electrochemical test results show that when the current density was 0.2 A/g

the specific capacity of PDDA-Si/G composite could reach 1439.9 (mA·h)/g and the Coulombic efficiency was above 98%. The specific capacity was 1209.3 (mA·h)/g after 80 cycles. The specific capacity still maintained 499.9 (mA·h)/g at a high current density (2 A/g).

关键词

Keywords

references

Li D D , Ding L X , Chen H B , et al . Novel nitrogen-rich porous carbon spheres as a high-performance anode material for lithium-ion batteries [J ] . J. Mater . Chem . A , 2014 , 2 ( 39 ): 16617-16622 .

Kong D Z , Luo J S , Wang Y L , et al . Three-dimensional Co 3 O 4 @MnO 2 hierarchical nanoneedle arrays: morphology control and electrochemical energy storage [J ] . Adv. Funct. Mater ., 2014 , 24 ( 24 ): 3815 - 3826 .

Son I H , Hwan P J , Kwon S , et al . Silicon carbide-free graphene growth on silicon for lithium-ion battery with high volumetric energy density [J ] . Nature Communications , 2015 , 6 ( 1 ): 8393 .

Ko M , Chae S , Jeong S , et al . Elastic a-silicon nanoparticle backboned graphene hybrid as a self-compacting anode for high-rate lithium ion batteries [J ] . ACS Nano , 2012 , 8 ( 8 ): 8591 .

Wu H , Zheng G , Liu N , et al . Engineering empty space between Si nanoparticles for lithium-ion battery anodes [J ] . Nano Letters , 2012 , 12 ( 2 ): 904 .

Ji J , Ji H , Zhang L L , et al . Graphene-encapsulated Si on ultrathin-graphite foam as anode for high capacity lithium-ion batteries [J ] . Advanced Materials , 2013 , 25 ( 33 ): 4673 - 4677 .

Zhao C , Yu C , Qiu B , et al . Ultrahigh rate and long-life sodium-ion batteries enabled by engineered surface and near-surface reactions [J ] . Advanced Materials , 2018 , 30 ( 7 ): 1702486 .

Yao W Q , Chen J , Zhan L , et al . Two-dimensional porous sandwich-like C/Si-graphene-Si/C nanosheets for superior lithium storage [J ] . ACS Applied Materials & Interfaces , 2017 , 9 ( 45 ): 39371-39379 .

Fang C C , Deng Y F , Xie Y , et al . The improved electrochemical performance of Si nanoparticle anode material by synergistic strategies of polydopamine and graphene oxide coatings [J ] . Journal of Physical Chemistry C , 2015 , 119 ( 4 ): 1720 - 1728 .

何大方 , 李丽鲜 , 白凤娟 , 等 . 结构有序的Si/void/C/graphene纳米复合结构的制备及储锂性能 [J ] . 化工学报 , 2017 , 68 ( 9 ): 3600 - 3606 .

He D F , Li L X , Bai F J , et al . Design, preparation, and lithium-storage properties of ordered Si/void/C/graphene nanocomposites [J ] . CIESC Journal , 2017 , 68 ( 9 ): 3600 - 3606 .

Han Y , Zou J , Li Z , et al . Si@void@C nanofibers fabricated using a self-powered electrospinning system for lithium-ion batteries [J ] . ACS Nano , 2018 , 12 ( 5 ): 4835 - 4843 .

Li X H , Wu M Q , Feng T T , et al . Graphene enhanced silicon/carbon composite as anode for high performance lithium-ion batteries [J ] . RSC Advances , 2017 , 7 ( 76 ): 48286-48293 .

Son I H , Park J H , Park S , et al . Graphene balls for lithium rechargeable batteries with fast charging and high volumetric energy densities [J ] . Nature Communications , 2017 , 8 ( 1 ): 1561 .

孔丽娟 , 周晓燕 , 范赛英 , 等 . 组氨酸功能化石墨烯量子点@纳米硅负极材料的制备及电化学性能研究 [J ] . 化学学报 , 2016 , 74 ( 7 ): 620 - 628 .

Kong L J , Zhou X Y , Fan S Y , et al . Study on the synthesis and electrichemical performance of histidine-functionalized graphene quantum dots@silicon composite anode material [J ] . Acta Chimica Sinica , 2016 , 74 ( 7 ): 620 - 628 .

Liu Z J , Guo P Q , Liu B L , et al . Carbon-coated Si nanoparticles/reduced graphene oxide multilayer anchored to nanostructured current collector as lithium-ion battery anode [J ] . Applied Surface Science , 2017 , 396 : 41 - 47 .

An Y L , Fei H F , Zeng G F , et al . Green, scalable, and controllable fabrication of nanoporous silicon from commercial alloy precursors for high-energy lithium-ion batteries [J ] . ACS Nano , 2018 , 12 ( 5 ): 4993 - 5002 .

Liang G M , Qin X Y , Zou J S , et al . Electrosprayed silicon-embedded porous carbon microspheres as lithium-ion battery anodes with exceptional rate capacities [J ] . Carbon , 2018 , 127 : 424 - 431 .

Feng J K , Zhang Z , Ci L J , et al . Chemical dealloying synthesis of porous silicon anchored by in situ generated graphene sheets as anode material for lithium-ion batteries [J ] . Journal of Power Sources , 2015 , 287 : 177 - 183 .

Wei S , Hu R Z , Zhang H Y , et al . A long-life nano-silicon anode for lithium ion batteries: supporting of graphene nanosheets exfoliated from expanded graphite by plasma-assisted milling [J ] . Electrochimica Acta , 2016 , 187 : 1 - 10 .

Huang R A , Guo Y Z , Chen Z N , et al . An easy and scalable approach to synthesize three-dimensional sandwich-like Si/polyaniline/graphene nanoarchitecture anode for lithium ion batteries [J ] . Ceramics International , 2018 , 44 ( 4 ): 4282 - 4286 .

Lin N , Xu T J , Li T Q , et al . Controllable self-assembly of micro-nanostructured Si-embedded graphite/graphene composite anode for high-performance li-Ion batteries [J ] . ACS Applied Materials & Interfaces , 2017 , 9 ( 45 ): 39318-39325 .

Lee B , Liu T , Sun K K , et al . Submicron silicon encapsulated with graphene and carbon as a scalable anode for lithium-ion batteries [J ] . Carbon , 2017 , 119 : 438 - 445 .

Yue H W , Wang S Y , Yang Z B , et al . Ultra-thick porous films of graphene-encapsulated silicon nanoparticles as flexible anodes for lithium ion batteries [J ] . Electrochimica Acta , 2015 , 174 : 688 - 695 .

Luo Z P , Xiao Q Z , Lei G T , et al . Si nanoparticles/graphene composite membrane for high performance silicon anode in lithium ion batteries [J ] . Carbon , 2016 , 98 : 373 - 380 .

李海 , 吕春祥 . 炭涂层硅/石墨烯纳米复合材料的制备及其储锂性能 [J ] . 新型炭材料 , 2014 , 29 ( 4 ): 295 - 300 .

Li H , Lyu C X . Preparation and lithium storage performance of a carbon-coated Si/graphene nanocomposite [J ] . New Carbon Materials , 2014 , 29 ( 4 ): 295 - 300 .

Chang P , Liu X , Zhao Q , et al . Constructing three-dimensional honeycombed graphene/silicon skeletons for high-performance Li-ion batteries [J ] . ACS Applied Materials & Interfaces , 2017 , 9 ( 37 ): 31879 .

张兴帅 , 许笑目 , 郭玉忠 , 等 . 锂离子电池Si/RGO@PANI三明治纳米结构负极材料的制备与电化学性能 [J ] . 无机化学学报 , 2017 , 33 ( 3 ): 377 - 382 .

Zhang X S , Xu X M , Guo Y Z , et al . Preparation and electrochemical properties of sandwich-like Si/RGO@PANI nanocomposites as anode for lithium ion battery [J ] . Chinese Journal of Inorganic Chemistry , 2017 , 33 ( 3 ): 377 - 382 .

刘超 , 文豪 , 张楚虹 . 自支撑纳米硅/石墨烯复合纸柔性电极的制备及其电化学性能的研究 [J ] . 材料导报 , 2016 , 30 ( 18 ): 26 - 29 .

Liu C , Wen H , Zhang C H . Preparation of free-standing flexible nano-silicon/graphene composite paper electrode for lithium-ion batteries [J ] . Materials Review , 2016 , 30 ( 18 ): 26 - 29 .

Shang H , Zuo Z C , Yu L , et al . Low-temperature growth of all-carbon graphdiyne on a silicon anode for high-performance lithium-ion latteries [J ] . Advanced Materials , 2018 : 1801459 .

Zhu C R , Chao D L , Sun J , et al . Enhanced lithium storage performance of CuO nanowires by coating of graphene quantum dots [J ] . Advanced Materials Interfaces , 2015 , 2 ( 2 ): 239 - 245 .

Zhang Y T , Zhang K B , Jia K L , et al . Preparation of coal-based graphene quantum dots/α-Fe 2 O 3 nanocomposites and their lithium-ion storage properties [J ] . Fuel , 2019 , 241 : 646 - 652 .

Wang Z L , Xu D , Wang H G , et al . In situ fabrication of porous graphene electrodes for high-performance energy storage [J ] . ACS Nano , 2013 , 7 ( 3 ): 2422 - 2430 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Fabrication and electrochemical capacitive performance of PANI/coal-based three-dimensional graphene

Research on application of alloy catalysts in electrochemical ammonia synthesis

Synthesis and sodium ion storage properties of cation exchange resin based mesoporous graphitic carbon

Microwave induced construction of highly dispersed Pd/FeP catalysts and their electrocatalytic performance

Preparation and microwave absorption properties of carbon nanofibers embedded with ultra-small CeO2 nanoparticles

Related Author

ZHANG Yating

REN Shaozhao

LI Jingkai

LI Keke

DANG Yongqiang

LIU Guoyang

QIU Jieshan

JI Zhijiao

Related Institution

College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology

School of Chemical Engineering and Technology, Xi'an Jiaotong University

National Institute of Clean-and-Low-Carbon Energy, China Energy Investment

School of Chemistry and Chemical Engineering, Hefei University of Technology

National Engineering Research Center of Distillation Technology, School of Chemical Engineering and Technology, Tianjin University

⁰