Catalytic combustion of propane over Pd<italic style="font-style: italic"><sub>x</sub></italic>Pt<italic style="font-style: italic"><sub>y</sub></italic>-ZSM-5/Cordierite monolithic catalyst

Quan TANG; Yanglong GUO; Wangcheng ZHAN; Yun GUO; Li WANG; Yunsong WANG

doi:10.11949/j.issn.0438-1157.20181110

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Catalytic combustion of propane over Pd_xPt_y-ZSM-5/Cordierite monolithic catalyst

Catalysis\, kinetics and reactors | 更新时间：2026-07-24

- Catalytic combustion of propane over Pd_xPt_y-ZSM-5/Cordierite monolithic catalyst
- CIESC Journal Vol. 70, Issue 3, Pages: 944-950(2019)
- 作者机构：
  
  华东理工大学工业催化研究所，上海 200237
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20181110
  CLC： TE 991.1
- Received：02 October 2018，
  
  Revised：2018-11-01，
  
  Online First：24 July 2026，
  
  Published：05 March 2019
- 稿件说明：
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唐铨, 郭杨龙, 詹望成, 郭耘, 王丽, 王筠松. 用于丙烷催化燃烧的Pd_xPt_y-ZSM-5/Cordierite整体式催化剂[J]. 化工学报, 2019, 70(3): 944-950 DOI: 10.11949/j.issn.0438-1157.20181110.

TANG Quan, GUO Yanglong, ZHAN Wangcheng, GUO Yun, WANG Li, WANG Yunsong. Catalytic combustion of propane over Pd_xPt_y-ZSM-5/Cordierite monolithic catalyst[J]. CIESC Journal, 2019, 70(3): 944-950 DOI: 10.11949/j.issn.0438-1157.20181110.
唐铨, 郭杨龙, 詹望成, 郭耘, 王丽, 王筠松. 用于丙烷催化燃烧的Pd_xPt_y-ZSM-5/Cordierite整体式催化剂[J]. 化工学报, 2019, 70(3): 944-950 DOI: 10.11949/j.issn.0438-1157.20181110. DOI：

TANG Quan, GUO Yanglong, ZHAN Wangcheng, GUO Yun, WANG Li, WANG Yunsong. Catalytic combustion of propane over Pd_xPt_y-ZSM-5/Cordierite monolithic catalyst[J]. CIESC Journal, 2019, 70(3): 944-950 DOI: 10.11949/j.issn.0438-1157.20181110. DOI：

摘要

以ZSM-5分子筛、铝溶胶、硝酸钯、硝酸铂和水为原料制备分子筛浆料，采用真空抽提-一次涂覆法在堇青石蜂窝陶瓷载体表面制备出Pd

-ZSM-5/Cordierite整体式催化剂，考察了Pd负载量、ZSM-5分子筛的硅铝比和Pd/Pt质量比对整体式催化剂的丙烷催化燃烧性能的影响，并用超声波振荡、SEM、XRD、H

-TPR和C

-TPD等手段对整体式催化剂进行了表征。当球磨时间为60 min，分子筛浆料固含量为38%时，整体式催化剂的涂层上载量可达到178 g‧L

-1

，涂层脱落率低于0.5%。Pd

-ZSM-5/Cordierite整体式催化剂（贵金属总负载量为1.2 g‧L

-1

）对于丙烷的催化燃烧具有较好的催化活性（

=259℃，

=323℃）和稳定性，具有良好的工业应用前景，其中较低的ZSM-5分子筛硅铝比以及Pd和Pt之间的相互作用增加了对丙烷的吸附能力和表面活性氧物种的数量，从而提高了整体式催化剂的催化活性。

Abstract

-ZSM-5/Cordierite monolithic catalysts were prepared on the

surface of the cordierite honeycomb supports

via

vacuum extraction and one coating method

in which ZSM-5 molecular sieve

alumina sol

platinum or palladium nitrates and water were used as raw materials to prepare molecular sieve slurry. Effects of Pd loading

Si/Al ratio of ZSM-5

the mass ratio of Pd/Pt on the catalytic performance of the monolithic catalysts for the catalytic combustion of propane were investigated. The monolithic catalysts were characterized by ultrasonic oscillation

SEM

XRD

-TPR and C

-TPD. When the ball milling time is 60 min and the molecular sieve slurry solid content is 38%

the coating amount of the monolith catalyst can reach 178 g‧L

-1

and the coating detachment rate is less than 0.5%. Pd

-ZSM-5/Cordierite catalyst (total loading of noble metals of 1.2 g‧L

-1

) exhibits better catalytic activity and stability (

=259℃

=323℃) for the catalytic combustion of propane

which has better industrial application prospect. Lower Si/Al ratio of ZSM-5 and the interaction between Pd and Pt increase the amounts of adsorbed propane and surface active oxygen species

thus increases the catalytic performance of the monolithic catalyst.

关键词

Keywords

references

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⁰

Catalytic combustion of propane over PdxPty-ZSM-5/Cordierite monolithic catalyst

DOI：10.11949/j.issn.0438-1157.20181110

摘要

Abstract

关键词

Keywords

references

Catalytic combustion of propane over Pd_xPt_y-ZSM-5/Cordierite monolithic catalyst