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1.中国石油大学(华东)山东省油气储运安全省级重点实验室,山东 青岛 266580
2.中国石油天然气股份有限公司 油气储运重点实验室,山东 青岛 266580
Received:02 July 2018,
Revised:2018-11-06,
Published:05 January 2019
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王财林, 顾帅威, 李玉星, 胡其会, 滕霖, 王婧涵, 马宏涛, 张大同. CO2-原油体系发泡特性实验研究[J]. 化工学报, 2019, 70(1): 251-260 DOI: 10.11949/j.issn.0438-1157.20180716.
WANG Cailin, GU Shuaiwei, LI Yuxing, HU Qihui, TENG Lin, WANG Jinghan, MA Hongtao, ZHANG Datong. Experimental study on foaming characteristics of CO2-crude oil mixture[J]. CIESC Journal, 2019, 70(1): 251-260 DOI: 10.11949/j.issn.0438-1157.20180716.
王财林, 顾帅威, 李玉星, 胡其会, 滕霖, 王婧涵, 马宏涛, 张大同. CO2-原油体系发泡特性实验研究[J]. 化工学报, 2019, 70(1): 251-260 DOI: 10.11949/j.issn.0438-1157.20180716. DOI:
WANG Cailin, GU Shuaiwei, LI Yuxing, HU Qihui, TENG Lin, WANG Jinghan, MA Hongtao, ZHANG Datong. Experimental study on foaming characteristics of CO2-crude oil mixture[J]. CIESC Journal, 2019, 70(1): 251-260 DOI: 10.11949/j.issn.0438-1157.20180716. DOI:
为研究CO
2
驱油田分离器内泡沫层产生及消除机理,设计了一套高压溶气原油泡沫测试系统,采用降压法研究了CO
2
-原油体系的发泡特性。利用高速摄像机对泡沫产生至衰变的演变过程进行了记录,总结分析了不同降压阶段的气泡行为,研究了降压速率和搅拌速率对原油发泡特性的影响规律。研究发现,随压力降低,稳定存在气泡的直径增大,气泡位置上移,发泡行为更加剧烈;降压速率增加对降压阶段的发泡行为无明显影响,但会加剧稳定工作压力下的发泡行为;在转速小于等于120 r/min的条件下,搅拌速率增加会加剧降压阶段的发泡行为,但会加速稳定工作压力下的泡沫衰变。
CO
2
enhanced oil recovery (CO
2
-EOR) technique is a good choice that can not only limit global warming
but also cut the high cost of carbon capture and storage (CCS). CO
2
flooding produced fluid contains large amounts of CO
2
and a lot of foam will generate in the separation process due to decompression. To study the foaming characteristics of CO
2
-crude oil system in oilfield separators
an experimental system was designed to simulate the real environment. Depressurization method was used to study the foam behavior in the tests. The foaming process of dissolved crude oil could be divided into depressurization stage and stable working pressure stage. Foam evolution from generation to attenuation was recorded by high-speed camera
and foam behaviors at different stages were summarized and analyzed. Foaming process could be divided into five stages: bubble formation
arrangement with single layer
bubble coalescence
bubble breakage and multilayer stack. As pressure decreased
the diameters of stable bubbles increased and the foam position moved upwards
and foaming behavior became more violent. In addition
foam form in crude oil belonged to spherical foam and the Gibbs-Marangoni effect of foam was found in the tests. The attenuation mechanism and influencing factors of CO
2
foam were analyzed and it was found that gas diffusion was the main mechanism for CO
2
foam attenuation. Furthermore
the effects of depressurization rate and stirring rate on the properties of foam were studied. The results show that the increase in depressurization rate had no obvious effect on the foaming behavior in depressurization process while it would aggravate the foaming behavior under stable working pressure. When the rotation speed is less than or equal to 120 r/min
the increase of the stirring rate will aggravate the foaming behavior in the depressurization stage
but accelerate the foam decay under stable working pressure.
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