Separation of copper and arsenic in copper smelting dust by Na<sub>2</sub>S-NaOH leaching assisted with ultrasound method

YAO Yingying; GUO Li; HU Zhongqiu; QUAN Qu; DU Dongyun

doi:10.11949/j.issn.0438-1157.20180406

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Separation of copper and arsenic in copper smelting dust by Na₂S-NaOH leaching assisted with ultrasound method

更新时间：2025-12-10

- Separation of copper and arsenic in copper smelting dust by Na₂S-NaOH leaching assisted with ultrasound method
- CIESC Journal Issue 9, Pages: 3983-3992(2018)
- 作者机构：
  
  1. 中南民族大学资源与环境学院, 环境科学与工程研究所,湖北,武汉,430074
  2. 中国地质大学(武汉)环境学院, 生物地质与环境地质国家重点实验室,湖北,武汉,430074
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20180406
  CLC： 756
- Online First：05 September 2018，
  
  Published：05 September 2018
- 稿件说明：
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YAO Yingying, GUO Li, HU Zhongqiu, et al. Separation of copper and arsenic in copper smelting dust by Na₂S-NaOH leaching assisted with ultrasound method[J]. CIESC Journal, 2018, (9): 3983-3992. DOI: 10.11949/j.issn.0438-1157.20180406.
DOI：

YAO Yingying, GUO Li, HU Zhongqiu, et al. Separation of copper and arsenic in copper smelting dust by Na₂S-NaOH leaching assisted with ultrasound method[J]. CIESC Journal, 2018, (9): 3983-3992. DOI: 10.11949/j.issn.0438-1157.20180406. DOI：

摘要

采用超声辅助Na2S-NaOH浸取体系对铜冶炼烟灰进行研究，在NaOH、Na2S与烟灰质量比0.4：1，液固比20：1，反应温度75℃，反应时间5 min，超声功率80 W，搅拌速率400 r·min-1条件下，As浸出率为88.81%，Cu浸出率为0.025%，实现了Cu和As的有效分离。采用该方法处理后，与单独碱浸相比，As浸出率提高9.21%，烟灰中As含量由0.85%降至0.58%，Cu含量由2.21%增至2.30%，且As浸出毒性浓度由12.66 mg·L-1降至2.84 mg·L-1，为烟灰的资源化利用创造了条件。超声辅助碱浸除砷动力学满足收缩核混合反应控制模型，表观活化能0.114 kJ·mol-1。XRD、XPS和重金属形态分析结果表明，超声空化作用可使As（Ⅲ）氧化为As（Ⅴ），有利于As浸出，故超声过程强化有利于Cu和As在碱浸体系中的选择性分离。

Abstract

Selective leaching of arsenic and copper in copper smelting dust was investigated by Na2S-NaOH leaching process with assistance of ultrasound method. The results showed that ultrasound wave could enhance alkaline leaching capacity and separation of arsenic and copper. The corresponding leaching ratios of arsenic and copper reached to 88.81% and 0.025% at the condition of 5 min discharge time

80 W discharge power

mass ratio of Na2S

NaOH to ash 0.4:1

liquid-solid ratio 20:1

temperature 75℃ and stirring speed 400 r·min-1. The leaching process with Na2S-NaOH assistant with ultrasound reduced arsenic and increase copper content in soot from 0.85% to 0.58% and from 2.21% to 2.30%

and the leaching rate of As increased 9.21%

the leaching toxicity concentration of As was reduced from 12.66 mg·L-1to 2.84 mg·L-1

compared with alkaline leaching

respectively. Kinetics of alkaline assisted with ultrasound leaching of arsenic in copper smelting dust was controlled by hybrid reaction and its leaching kinetic equation followed the reacted shrinking core model

its apparent activation energy was 0.114 kJ·mol-1

and the reaction system was balanced within 5 min. XPS

XRD and speciation analysis of heavy metals indicated that ultrasound wave was able to oxidize As(Ⅲ) to As(Ⅴ)

which was propitious to leaching of arsenic. In conclusion

ultrasound wave assisted Na2S-NaOH leaching process proved to be an efficient way of removing both arsenic and copper from soot

so the soot could be further utilized after toxic content reduction.

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Separation of copper and arsenic in copper smelting dust by Na2S-NaOH leaching assisted with ultrasound method

DOI：10.11949/j.issn.0438-1157.20180406

摘要

Abstract

关键词

Keywords

references

Separation of copper and arsenic in copper smelting dust by Na₂S-NaOH leaching assisted with ultrasound method