Based on the need to increase the height of the exhaust plume and the whitening of the flue gas
the wet flue gas after the wet desulfurization of the flue gas of the coal-fired boiler must be properly disposed. However
the wet flue gas after wet desulfurization is very corrosive and will cause serious corrosion to downstream equipment. In this paper
in-plant corrosion tests were conducted in the flue after the wet desulphurization system in a 91 MW coal-fired travelling grate heating boiler. Five common corrosion-resistant steels including ND steel
304 L
316 L
2205 and 2507 were tested and then evaluated. According to the results
surface temperature of the steel was the key factor in corrosion process. As the surface temperature increased
corrosion of the steels was first exacerbated due to the increase in Cl
-
concentration in the deposits and then mitigated due to the lack of the electrolyte.
关键词
Keywords
references
Srivastava R K , Jozewicz W . Flue gas desulfurization: the state of the art [J]. Journal of the Air & Waste Management Association , 2001 , 51 ( 12 ): 1676 - 1688 .
Li W Y , Wang J X , Che J W . Analysis on corresponding problems of WFGD flue gas wet emission [J]. Proceedings of the CSEE , 2007 , 27 ( 14 ): 36 - 40 .
Ma X Y , Hui R T , Yang A Y , et al . Numerical analysis of wet plume formation mechanism and dissipation technique [J]. Science Technology and Engineering , 2017 , 17 ( 22 ): 220 - 224 .
Ma X Y , Hui R T , Yang A Y . Effects of wet plume elimination technology on pollutants diffusion [J]. Journal of Environmental Engineering Technology , 2017 , 7 ( 5 ): 533 - 538 .
Liu Y G , Luo Z Z , Chen G , et al . Cause analyses on typical operational problems of low temperature economizer and MGGH and proposed countermeasures [J]. Dongfang Electric Review , 2016 , 30 ( 2 ): 31 - 35 .
Darowicki K , Krakowiak S . Durability evaluation of Ni-Cr-Mo super alloys in a simulated scrubbed flue gas environment [J]. Anti-Corrosion Methods and Materials , 1999 , 46 ( 1 ): 19 - 22 .
Crum J R , Shoemaker L E , Stiltner G . The role of nickel alloys in fighting corrosion in wet limestone FGD systems [C]// CORROSION 96 , NACE International , 1996 .
Jansen P , Hansen V , Jensen T . Corrosion experience with carbon steel in spray absorption FGD plant [J]. Materials & Corrosion , 1992 , 43 ( 6 ): 310 - 315 .
Dahl L . Corrosion in flue gas desulfurization plants and other low temperature equipment [J]. Materials & Corrosion , 1992 , 43 ( 6 ): 298 - 304 .
Shoemaker L E , Crum J R . Experience in effective application of metallic materials for construction of FGD systems [R]. Special Metals , 2010 .
Pettersson R , Ekman S , Bergquist A , et al . Corrosion of austenitic and duplex stainless steels in flue gas cleaning systems for waste combustion processes [C]// CORROSION 2013 . NACE International , 2013 .
Zhao Y , Liang L , Zhang J L , et al . Flue gas wet desulphurization system corrosion environment and the comparison of ND steel and 316L corrosion resistance [J]. Journal of Shanghai University of Electric Power , 2016 , 32 ( 3 ): 216 - 220 .
Kim M T , Chang S Y , Oh O Y , et al . Failure analysis of enamel-coated carbon steel heating elements of gas-gas heater for flue gas desulfurization system [J]. Engineering Failure Analysis , 2007 , 14 ( 4 ): 686 - 693 .
Pan P Y , Chen H , Liang Z Y , et al . Experimental study on corrosion of steels for flue gas reheaters in a coal-fired power plant [J]. Applied Thermal Engineering , 2017 , 115 : 267 - 279 .
Zhao Q X , Yang W J , Sun Y R , et al . Key technologies of multi-pollutants synergia control in coa1-fired industrial boiler [J]. Industrial Boiler , 2015 , ( 6 ): 1 - 9 .
Mo H , Zhu J , Huang Z J , et al . Test and study on SO 3 removal performance of different wet flue gas desulfurization technologies at ultra-low pollutants emission [J]. Electric Power , 2017 , 50 ( 3 ): 46 - 50 .
Åmand L E , Bo L , Eskilsson D , et al . Deposits on heat transfer tubes during co-combustion of biofuels and sewage sludge [J]. Fuel , 2006 , 85 ( 10 ): 1313 - 1322 .
Liu K , Xie W , Li D , et al . The effect of chlorine and sulfur on the composition of ash deposits in a fluidized bed combustion system [J]. Theriogenology , 2000 , 54 ( 5 ): 757 - 769 .
Yamashita M , Konishi H , Kozakura T , et al . In situ observation of initial rust formation process on carbon steel under NaSO and NaCl solution films with wet/dry cycles using synchrotron radiation X-rays [J]. Corrosion Science , 2005 , 47 ( 10 ): 2492 - 2498 .
Tsutsumi Y , Nishikata A , Tsuru T . Pitting corrosion mechanism of Type 304 stainless steel under a droplet of chloride solutions [J]. Corrosion Science , 2007 , 49 ( 3 ): 1394 - 1407 .
Jin Z H , Ge H H , Lin W W , et al . Corrosion behaviour of 316L stainless steel and anti-corrosion materials in a high acidified chloride solution [J]. Applied Surface Science , 2014 , 322 : 47 - 56 .
Lee J S , Fushimi K , Nakanishi T , et al . Corrosion behaviour of ferrite and austenite phases on super duplex stainless steel in a modified green-death solution [J]. Corrosion Science , 2014 , 89 ( 89 ): 111 - 117 .
Wang Y , Wang W , Liu Y , et al . Study of localized corrosion of 304 stainless steel under chloride solution droplets using the wire beam electrode [J]. Corrosion Science , 2011 , 53 ( 9 ): 2963 - 2968 .
Ma Y , Li Y , Wang F . Corrosion of low carbon steel in atmospheric environments of different chloride content [J]. Corrosion Science , 2009 , 51 ( 5 ): 997 - 1006 .
Nishimura T . Electrochemical behaviour and structure of rust formed on Si- and Al-bearing steel after atmospheric exposure [J]. Corrosion Science , 2010 , 52 ( 11 ): 3609 - 3614 .
Rémazeilles C , Refait P . On the formation of β-FeOOH (akaganéite) in chloride-containing environments [J]. Corrosion Science , 2007 , 49 ( 2 ): 844 - 857 .
Corvo F , Betancourt N , Mendoza A . The influence of airborne salinity on the atmospheric corrosion of steel [J]. Corrosion Science , 1995 , 37 ( 12 ): 1889 - 1901 .