Preparation of ZIF-8 membranes on ZnO modified stainless steel nets

LI Jia; GU Jinghua; YIN Wenjie; LI Zeyao

doi:10.11949/j.issn.0438-1157.20180194

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Preparation of ZIF-8 membranes on ZnO modified stainless steel nets

更新时间：2025-12-10

- Preparation of ZIF-8 membranes on ZnO modified stainless steel nets
- CIESC Journal Issue 8, Pages: 3724-3731(2018)
- 作者机构：
  
  北京航空航天大学材料科学与工程学院,北京,100191
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20180194
  CLC： 614
- Online First：05 August 2018，
  
  Published：05 August 2018
- 稿件说明：
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LI Jia, GU Jinghua, YIN Wenjie, et al. Preparation of ZIF-8 membranes on ZnO modified stainless steel nets[J]. CIESC Journal, 2018, (8): 3724-3731.
DOI：

LI Jia, GU Jinghua, YIN Wenjie, et al. Preparation of ZIF-8 membranes on ZnO modified stainless steel nets[J]. CIESC Journal, 2018, (8): 3724-3731. DOI： 10.11949/j.issn.0438-1157.20180194.

摘要

ZIF-8因具有0.34 nm的孔道直径而被认为是最具应用前景的气体分离膜材料之一。不锈钢网（SSN）作为分离膜的支撑体具有价格低廉、易于裁剪、厚度薄等优点。采用水热法在SSN表面生长ZnO缓冲层，以ZnO修饰的SSN（ZnO/SSN）为支撑体制备ZIF-8膜。采用X射线衍射（XRD）和扫描电子显微镜（SEM）对合成的ZIF-8膜进行表征，并进行了气体渗透性能测试，结果表明，在ZnO颗粒修饰后的SSN支撑体上无需活化可制备出单一物相、无缺陷的ZIF-8膜；在室温（298 K）下，ZIF-8膜的H2/CO2、H2/N2、H2/CH4的理想分离系数分别为7.3、9.2、12.4；在150℃，ZIF-8膜的渗透性能稳定。

Abstract

ZIF-8 is one of the most perspective membrane materials for gas separation due to its regular pore size of 0.34 nm. Stainless steel nets (SSN) have the advantages of low price

easy cutting

and thin thickness as membrane substrates. In this work

ZnO buffering layer was synthesized on SSN substrate by hydrothermal method. ZIF-8 membranes were prepared on the ZnO modified SSN (ZnO/SSN) supports. ZnO/SSN supported ZIF-8 membranes were characterized by X ray diffraction (XRD) and scanning electron microscopy (SEM). The gas separation property of prepared ZIF-8 membranes was carried out. It is indicated that phase-pure and defect-free ZIF-8 membrane can be obtained on the ZnO/SSN substrate without additional activation step of ZnO layer. The ideal separation factors of H2/CO2

H2/N2 and H2/CH4 were 7.3

9.2 and 12.4 at room temperature. The membrane demonstrates a good stability of permeability at 150℃.

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