JIANG Yuliang, LIU Yuanwei, HAN Bo, et al. Preparation and properties of PEI crosslinked PECH/nylon composite anion exchange membrane[J]. CIESC Journal, 2018, (6): 2744-2752.
DOI:
JIANG Yuliang, LIU Yuanwei, HAN Bo, et al. Preparation and properties of PEI crosslinked PECH/nylon composite anion exchange membrane[J]. CIESC Journal, 2018, (6): 2744-2752.DOI: 10.11949/j.issn.0438-1157.20171394.
Preparation and properties of PEI crosslinked PECH/nylon composite anion exchange membrane
with good stability and membrane-forming properties
and the use of polyepichlorohydrin (PECH) polymer as a matrix to prepare anion exchange membrane
which can avoid the use of carcinogenic substances chloromethyl ether
and dicyclopentyl ether. However
the prepared membrane with PECH as matrix has the disadvantages of poor mechanical strength and high water absorption
which limits its wide application in electrodialysis technology. Crosslinking reaction with PECH was carried out by using polyethyleneimine (PEI) as crosslinking agent
and a network structure is formed therein to limit the excessive swelling of the polymer membrane in water
thus to enhance the mechanical strength of the membrane
and introduction of nylon mesh to further improve the mechanical properties of the membrane. In the present work
the QCPECH/nylon composite anion exchange membrane was prepared. The effects of water uptake
swelling degree
ion exchange capacity
mechanical strength
membrane resistance and desalination on the composite anion exchange membrane were investigated. The results showed that the desalination efficiency (94.8%) of the prepared P1 membrane is higher than that of the commercial membrane (92.4%). It can be seen that the composite anion exchange membrane made of PECH/nylon crosslinked with PEI has the potential for development in electrodialysis desalination.