Preparation of porous carbon material from starch and it's performance for separation of CO<sub>2</sub>/CH<sub>4</sub>

CHEN Minling; WANG Xingjie; XIAO Jing; XIA Qibin; LI Zhong

doi:10.11949/j.issn.0438-1157.20171080

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Preparation of porous carbon material from starch and it's performance for separation of CO₂/CH₄

更新时间：2025-12-10

- Preparation of porous carbon material from starch and it's performance for separation of CO₂/CH₄
- CIESC Journal Issue 1, Pages: 455-463(2018)
- 作者机构：
  
  1. 华南理工大学化学与化工学院,广东,广州,510640
  2. 亚热带建筑国家重点实验室,广东,广州,510640
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20171080
  CLC： 641TQ-9
- Online First：05 January 2018，
  
  Published：05 January 2018
- 稿件说明：
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CHEN Minling, WANG Xingjie, XIAO Jing, et al. Preparation of porous carbon material from starch and it's performance for separation of CO₂/CH₄[J]. CIESC Journal, 2018, (1): 455-463. DOI: 10.11949/j.issn.0438-1157.20171080.
DOI：

CHEN Minling, WANG Xingjie, XIAO Jing, et al. Preparation of porous carbon material from starch and it's performance for separation of CO₂/CH₄[J]. CIESC Journal, 2018, (1): 455-463. DOI: 10.11949/j.issn.0438-1157.20171080. DOI：

摘要

以淀粉为原料，使用水热法将其碳化后用活化剂KOH对其活化，制备了淀粉基多孔碳材料，并对其进行结构表征和CO2/CH4的吸附性能测试，计算吸附热以及材料对CO2/CH4的吸附选择性，讨论了碳材料结构对其吸附性能的影响。结果表明：在制备过程中，随着活化剂KOH用量比例的增大，所制得的材料其比表面积和孔容增大，其孔径分布也就越宽。所制得的碳材料其比表面积可达2972 m2·g-1。这些淀粉基多孔碳材料对水蒸气的吸附等温线呈现出Ⅳ类等温线。所制备材料对CO2吸附容量主要取决于其孔径小于0.8 nm的累积孔容（Vd < 0.8 nm）。材料的超微孔的孔容越大，其对CO2吸附容量也越大。所制备的C-KOH-1材料在101325 Pa和298 K条件下，对CO2的吸附量达到4.2 mmol·g-1，其对CO2的吸附热明显高于其对CH4吸附热，其对CO2/CH4吸附选择性为3.7～4.26，同时本文通过对材料的水蒸气吸附等温线进行测试，结果表明所得材料主要表现为中等憎水性，这对材料在实际工况的应用奠定了基础。

Abstract

In this work

porous carbon materials were prepared by using starch as carbon source. The starch first went through polymerization under hydrothermal condition and followed by a KOH activation. Their structures and adsorption performances for CO2 and CH4 were characterized and tested. The isosteric heat of adsorption and the selectivity toward CO2/CH4 were estimated based on the adsorption isotherms

and the effect of carbon material structure on its adsorption properties was also discussed. The results showed that the specific surface area and pore volume of the prepared materials increased as more KOH was used

and the pore size distribution also became wider. The derived carbon material had a high specific surface area of 2972 m2·g-1

the H2O adsorption isotherms of the materials showed an IV-typed isotherm. It was found that the CO2 adsorption capacity of the materials mainly depended on the cumulative pore volume with pore size less than 0.8 nm. That is

the larger the ultramicro pore volume(Vd < 0.8 nm) of the material

the greater the CO2 adsorption capacity at 298 K and 101325 Pa. The CO2 adsorption amount on the C-KOH-1 was 4.2 mmol·g-1 in our work

and the isosteric heat of CO2 adsorption was higher than that of CH4

the selectivity toward CO2/CH4 is in the range of 3.7-4.26. At the same time

the water adsorption isotherms of the materials were also examined and the results showed that the materials were mainly hydrophobic

which can be a potential adsorbent being used in the reality.

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Preparation of porous carbon material from starch and it's performance for separation of CO2/CH4

DOI：10.11949/j.issn.0438-1157.20171080

摘要

Abstract

关键词

Keywords

references

Preparation of porous carbon material from starch and it's performance for separation of CO₂/CH₄