Enhanced nitrobenzene removal by persulfate-assisted zerovalent iron

FAN Peng; CHEN Jie; GUAN Xiaohong; QIAO Junlian

doi:10.11949/j.issn.0438-1157.20171065

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Enhanced nitrobenzene removal by persulfate-assisted zerovalent iron

更新时间：2025-12-10

- Enhanced nitrobenzene removal by persulfate-assisted zerovalent iron
- CIESC Journal Issue 5, Pages: 2175-2182(2018)
- 作者机构：
  
  同济大学环境科学与工程学院,上海,200092
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20171065
  CLC： 522X592
- Online First：05 May 2018，
  
  Published：05 May 2018
- 稿件说明：
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FAN Peng, CHEN Jie, GUAN Xiaohong, et al. Enhanced nitrobenzene removal by persulfate-assisted zerovalent iron[J]. CIESC Journal, 2018, (5): 2175-2182.
DOI：

FAN Peng, CHEN Jie, GUAN Xiaohong, et al. Enhanced nitrobenzene removal by persulfate-assisted zerovalent iron[J]. CIESC Journal, 2018, (5): 2175-2182. DOI： 10.11949/j.issn.0438-1157.20171065.

摘要

考察了过硫酸盐（PS）强化零价铁（ZVI）对水中硝基苯去除的性能。结果表明在单纯利用ZVI还原去除硝基苯过程中，初始pH 3.0时初期去除硝基苯速率较快，初始pH 4.0～7.0时随pH的升高反应速率减慢，而ZVI投量的增加对去除速率有较大提升作用。向体系中投加PS能显著促进零价铁去除硝基苯的速率，在达到相同去除效果的情况下，外加PS的成本远远小于提升ZVI投量所引起的成本增加。综合固体产物的XRD表征得知，PS提高ZVI去除硝基苯的效果主要是通过促进ZVI的腐蚀和改变ZVI腐蚀产物的种类来实现。通过FTIR表征可知，外加PS仅对硝基苯去除过程起加速作用，而不改变其还原路径。GC-MS的结果则验证了硝基苯被ZVI/ZVI-PS降解的主要产物为苯胺。

Abstract

The removal of nitrobenzene in the zerovalent iron-persulfate (ZVI-PS) system was investigated in this study. During the process of nitrobenzene reduction by pristine ZVI

fast adsorption of nitrobenzene was observed at pHini 3.0 and the removal rate was accelerated with the decrease of initial pH values. The increase of ZVI dosage enhanced the removal effectively and PS added to the system significantly promoted the removal rate of nitrobenzene. The cost of PS added was far less than the increase of counterpart of ZVI dosage to achieve the same removal effect. By XRD characterization of the precipitates after reaction

PS was supposed to enhance nitrobenzene removal by promoting ZVI corrosion and transformation of ZVI corrosion products. By FTIR characterization

it was determined that PS accelerated the nitrobenzene reduction process only

but did not change its reduction pathway. GC-MS results verified that the main product of nitrobenzene reduction by ZVI/ZVI-PS was aniline.

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