SUN Xuhui, QI Yuan, DONG Shuyu. Copper corrosion inhibition mechanism by combination of 2-mercaptobenzothiazole and magnetic treatment[J]. CIESC Journal, 2018, (5): 2120-2126.
DOI:
SUN Xuhui, QI Yuan, DONG Shuyu. Copper corrosion inhibition mechanism by combination of 2-mercaptobenzothiazole and magnetic treatment[J]. CIESC Journal, 2018, (5): 2120-2126.DOI: 10.11949/j.issn.0438-1157.20171062.
Copper corrosion inhibition mechanism by combination of 2-mercaptobenzothiazole and magnetic treatment
In order to investigate whether magnetic treatment and 2-mercaptobenzothiazole (MBT) have synergistic effect on corrosion inhibition
corrosion rate of red copper was measured under different treatment conditions by weight loss method. The treatments included permanent magnetic field
alternative magnetic field
corrosion inhibitor MBT
and combination of MBT and magnetic field. Mechanism of corrosion inhibition was studied with assistance of SEM
XRD and ATR-FTIR. The results showed that permanent magnetic field had little effect on corrosion inhibition
but alternative magnetic field had some improvement on corrosion inhibition by forming compact oxide film on copper surface. Alternative magnetic field reduced water polarity and gave water molecules power and activity
which increased MBT solubility in water and adsorbance on copper surface. Therefore
combination of alternative magnetic field and MBT has synergistic effect on corrosion inhibition. To achieve same corrosion inhibition effect as MBT itself
synergistic effect could decrease MBT usage by 60%. Because MBT is dissolved in NaOH solution
less MBT will reduce alkali consumption and lower conductivity of cooling water in power generator.