LI Qiaole, YAN Yinglin, YANG Rong, et al. Electrochemical performance of activated carbon derived from corn bracts/sulfur composite cathode material for lithium-sulfur batteries[J]. CIESC Journal, 2017, (11): 4376-4382.
DOI:
LI Qiaole, YAN Yinglin, YANG Rong, et al. Electrochemical performance of activated carbon derived from corn bracts/sulfur composite cathode material for lithium-sulfur batteries[J]. CIESC Journal, 2017, (11): 4376-4382.DOI: 10.11949/j.issn.0438-1157.20170340.
Electrochemical performance of activated carbon derived from corn bracts/sulfur composite cathode material for lithium-sulfur batteries
Lithium sulfur batteries are considered to be the most promising secondary battery because of its high theoretical specific capacity (1675 mA·h·g-1). However
the sulfur cathode faces the challenges
such as poor conductivity
low utilization of sulfur and poor structure stability of cathode. Biomass-based porous carbon
with cheap and accessible agricultural waste corn bracts as raw material
was prepared by chemical activation with KOH
and then composited with sublimate sulfur through modelling-fused method to form sulfur/carbon composite. The microscopic structure and morphology of the composites were characterized by XRD
SEM
TEM
and BET. The results show that the biomass-based porous carbon material possesses lamellar structure
which is similar to graphene
and abundant mesoporous structure on the surface of carbon. Furthermore
sulfur particles homogeneously distribute in the carbon conductive network. In addition
the electrochemical properties were studied by galvanostatic charge-discharge tests and electrochemical impedance spectroscopy. The results show that the battery possesses high discharge capacity and good cycle-life performance. The main reasons are as follow:the porous carbon structure like graphene
enhancing conductivity of sulfur cathode; the huge specific surface area which make electrochemical reaction sites increased
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