Volatility and catalysis of trace elements during oil shale pyrolysis

HE Lu; WANG Li; MA Yue; LI Shuyuan

doi:10.11949/j.issn.0438-1157.20170297

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Volatility and catalysis of trace elements during oil shale pyrolysis

更新时间：2025-12-10

- Volatility and catalysis of trace elements during oil shale pyrolysis
- CIESC Journal Issue 10, Pages: 3912-3922(2017)
- 作者机构：
  
  中国石油大学(北京)理学院,北京,102249
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20170297
  CLC： Q51
- Online First：05 October 2017，
  
  Published：05 October 2017
- 稿件说明：
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HE Lu, WANG Li, MA Yue, et al. Volatility and catalysis of trace elements during oil shale pyrolysis[J]. CIESC Journal, 2017, (10): 3912-3922.
DOI：

HE Lu, WANG Li, MA Yue, et al. Volatility and catalysis of trace elements during oil shale pyrolysis[J]. CIESC Journal, 2017, (10): 3912-3922. DOI： 10.11949/j.issn.0438-1157.20170297.

摘要

利用电感耦合等离子质谱仪（ICP-MS）测定油页岩样品和不同终温下热解半焦中13种金属微量元素的含量，分析这些元素在样品中的含量分布特征及其迁移规律。结果显示：龙口油页岩中富集Ba、Cd，巴里坤油页岩中富集Ba、Cd、Li、V、Sb，且样品中多数微量元素在500℃时挥发性最强。将不同形态的微量元素负载于干酪根上并进行热重分析，根据热重结果计算其动力学，再通过裂解气质联用实验（PY-GC/MS）测定干酪根和浸渍硝酸镍的干酪根热解时烷烃类产物的相对含量，研究微量元素对干酪根热解生烃转化率、热解速率以及产物分布的影响。结果表明：微量元素的盐类可以催化干酪根热解生烃，增大其热解转化率和热解速率，提高轻组分烷烃产率，降低重组分烷烃产率。

Abstract

Inductively coupled plasma mass spectrometer (ICP-MS) has been used to determine the concentration of Li

and Pb in oil shale samples and semi-cokes pyrolyzed at different final temperatures.The results show that Balikun oil shale contains more trace elements

especially Ba

V and Sb

compared with Longkou oil shale which is only rich in Ba and Cd

and that most trace elements volatilize at around 500℃.In addition

the influence of trace elements on kerogen pyrolysis was studied.Thermogravimetric analyzer was used to investigate pyrolysis kinetics of kerogen with trace elements in different forms.The kinetic parameters (apparent activation energy E and frequency factor A) were calculated using overall n order reaction procedure.The relative content of alkane products was characterized by pyrolysis-gas chromatography/mass spectrometer (PY-GC/MS).The results indicate that Ni (NO3)2 can catalyse kerogen pyrolysis by increasing its conversion

rate and yields of light alkane products and decreasing yields of heavy alkane products.

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