Effects of demineralization methods on structure and reactivity of Zhundong subbituminous coal

ZHANG Wenda; WANG Pengxiang; SUN Shaozeng; ZHAO Yijun; ZHAO Hongxiang; YAN Taisen; WU Jiangquan

doi:10.11949/j.issn.0438-1157.20161821

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Effects of demineralization methods on structure and reactivity of Zhundong subbituminous coal

更新时间：2025-12-10

- Effects of demineralization methods on structure and reactivity of Zhundong subbituminous coal
- CIESC Journal Issue 8, Pages: 3291-3300(2017)
- 作者机构：
  
  哈尔滨工业大学能源科学与工程学院,黑龙江,哈尔滨,150001
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20161821
  CLC： 382.1
- Online First：05 August 2017，
  
  Published：05 August 2017
- 稿件说明：
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ZHANG Wenda, WANG Pengxiang, SUN Shaozeng, et al. Effects of demineralization methods on structure and reactivity of Zhundong subbituminous coal[J]. CIESC Journal, 2017, (8): 3291-3300.
DOI：

ZHANG Wenda, WANG Pengxiang, SUN Shaozeng, et al. Effects of demineralization methods on structure and reactivity of Zhundong subbituminous coal[J]. CIESC Journal, 2017, (8): 3291-3300. DOI： 10.11949/j.issn.0438-1157.20161821.

摘要

研究酸洗脱灰过程对煤的化学结构和反应活性的影响对煤的清洁高效利用十分重要。采用HCl-HF-HCl和HF-HNO3-HCl两种方法对准东次烟煤进行处理，利用傅里叶红外光谱对原煤及其酸洗处理得到的脱灰煤进行结构表征，并用微型流化床多阶段气固反应分析仪对煤粉样品燃烧反应性进行分析。结果表明，酸洗处理可使煤中灰分含量降低到0.2%以下，脱灰煤中OH和COOH附近的吸收峰强度显著增强，脂肪侧链变短，芳香环上取代基减少。HF使得煤中硅铝类矿物质被大量脱除，HNO3会与煤中有机物发生硝化反应，导致部分含氧官能团含量进一步增加。当温度在600和700℃时，脱灰煤燃烧反应性与原煤相比显著降低，但随着温度升高至800和900℃，脱灰煤与原煤的反应性差距变小。

Abstract

It is critical for clean and efficient utilization to study the effects of the demineralization process on the chemical structure and reactivity of coals. In the study

Zhundong raw coal was processed using HCl-HF-HCl and HF-HNO3-HCl methods. The structures of both the raw coal and demineralized-coal were characterized by FT-IR

and their reactivities were analyzed by using a micro fluidized bed multistage gas-solid reaction analyzer. The results show that acid treatment is able to reduce the ash content of coal to the level under 0.2%. The intensity of absorption peaks near OH and COOH in demineralized coal was significantly enhanced. The aliphatic side chains and the substituent on aromatic ring became shorter. A huge amount of silicon and aluminum minerals were removed by the HF treatment process. HNO3 can react with organic matter in coal which leads to further increase in the content of oxygen functional groups. The combustion reactivity of demineralized coal is significantly lower than the raw coal at 600℃ and 700℃

but as the temperature rises to 800℃ and 900℃

the difference of combustion reactivity between the two kinds of demineralized coal and the raw coal becomes smaller.

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