MO Chun, LIAO Wenjie, LIANG Bin, et al. Life-cycle greenhouse gas emissions and cost of potassium extraction and CO2 mineralization via K-feldspar—industrial solid waste calcination[J]. CIESC Journal, 2017, (6): 2501-2509. DOI: 10.11949/j.issn.0438-1157.20161754.
DOI:
MO Chun, LIAO Wenjie, LIANG Bin, et al. Life-cycle greenhouse gas emissions and cost of potassium extraction and CO2 mineralization via K-feldspar—industrial solid waste calcination[J]. CIESC Journal, 2017, (6): 2501-2509. DOI: 10.11949/j.issn.0438-1157.20161754.DOI:
Life-cycle greenhouse gas emissions and cost of potassium extraction and CO2 mineralization via K-feldspar—industrial solid waste calcination
利用工业固废活化非水溶性钾长石矿,矿化固定二氧化碳(CO2)并提钾工艺,是同时处理工业固废、开发钾资源、减排CO2等一举多得的CCUS路线。采用生命周期评价(LCA)方法,以生产含1 t K2O的钾肥为功能单元,以传统的高炉冶炼钾长石制可溶性钾肥并联产白水泥工艺作为参照,对比评价了两种钾长石-工业固废体系矿化CO2联产钾肥工艺过程的碳减排潜力和经济性。对工艺从原料开采、运输到产品生产的生命周期的温室气体排放量(简称“碳排放”)和成本进行了全流程的核算,研究了更全面的产品碳排放和成本分配方法。结果表明,无论是碳排放还是经济性,钾长石-工业固废体系矿化CO2联产钾肥工艺均较传统工艺有很大提高,碳减排潜力分别可达81.16%和20.48%左右,成本可节约34.75%和45.11%左右。
Abstract
Using industrial solid waste to calcinate non-water-soluble natural K-feldspar for CO2 mineralization and potassium extraction is a multi-functional CO2 capture
utilization and storage (CCUS) technology that can treat industrial solid waste
utilize potassium resource and reduce greenhouse-gas (GHG) emissions. Life cycle assessment (LCA) was adopted based on a functional unit of the produced potash fertilizer containing 1 ton of K2O to compare two emerging technologies of simultaneous potash fertilizer production and CO2 mineralization from K-feldspar and industrial solid waste (CaCl2/phosphor-gypsum) with a traditional technology of potash fertilizer and white cement coproduction by smelting K-feldspar in blast furnace in terms of GHG-reduction potential and economic feasibility. The life-cycle (from raw material exploitation to transportation to production) GHG emissions and life-cycle cost of these technologies were accounted by using an improved allocation approach that considered the credit of avoided GHG emissions/cost from industrial solid waste treatment. The results showed that the two emerging technologies were preferred to the traditional technology in terms of both life-cycle GHG emissions and economic feasibility with GHG-reduction potential of about 81.16% and 20.48%
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