Preparation and properties of iron doped TiO<sub>2</sub> hollow microspheres

LI Yabo; ZHENG Yuying; LIU Yanglong

doi:10.11949/j.issn.0438-1157.20160443

您当前的位置：

首页 >

文章列表页 >

Preparation and properties of iron doped TiO₂ hollow microspheres

更新时间：2025-11-26

- Preparation and properties of iron doped TiO₂ hollow microspheres
- CIESC Journal Vol. 67, Issue 10, Pages: 4493-4499(2016)
- 作者机构：
  
  1. 福州大学材料科学与工程学院,福建,福州,350108
  2. 福州大学石油化工学院,福建,福州,350108
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20160443
  CLC： Q032
- Online First：05 October 2016，
  
  Published：05 October 2016
- 稿件说明：
移动端阅览
LI Yabo, ZHENG Yuying, LIU Yanglong. Preparation and properties of iron doped TiO₂ hollow microspheres[J]. CIESC Journal, 2016, 67(10): 4493-4499. DOI: 10.11949/j.issn.0438-1157.20160443.
DOI：

LI Yabo, ZHENG Yuying, LIU Yanglong. Preparation and properties of iron doped TiO₂ hollow microspheres[J]. CIESC Journal, 2016, 67(10): 4493-4499. DOI: 10.11949/j.issn.0438-1157.20160443. DOI：

摘要

以TiF4为钛源、九水合硝酸铁为掺杂前体，采用水热法制备铁掺杂的TiO2空心微球。采用SEM、TEM、XRD、BET、XPS等技术对样品的形貌、结构、晶型、比表面积、元素组成等进行表征，以亚甲基蓝（MB）的光催化降解为目标反应，评价其光催化活性。结果表明，160℃下水热反应生成的纳米TiO2空心微球晶型为锐钛矿，少量掺铁并不影响微球的形貌及晶体结构。光催化实验表明，160℃下水热反应12 h生成的TiO2空心微球样品均匀性好、光催化活性最佳；铁掺杂能显著提高TiO2空心微球的催化活性，当铁钛比为1.5:100时，所得样品粒径最小，比表面积最大，光催化活性最高。

Abstract

Iron-doped titanium dioxide hollow microspheres were prepared hydrothermally using titanium tetrafluoride and ferric nitrate nonahydrate in aqueous solution as starting materials

and were characterized by scanning electron microscopy (SEM)

transmission electron microscopy (TEM)

X-ray diffraction (XRD)

surface area (BET) and X-ray photoelectron spectroscopy (XPS). Photocatalytic activity of the microspheres was evaluated on photocatalytic degradation of aqueous methylene blue (MB). TiO2 in hollow microspheres created at 160℃ were anatase crystal and doping a relatively small amount of iron did not alter morphology and crystal structure of TiO2. Iron doping could significantly improve the photocatalytic activity of TiO2 hollow microspheres. The TiO2 hollow microspheres obtained at a condition of 160℃ for 12 h had optimal dimensional uniformity and photocatalytic activity

which the best photocatalytic effect were observed on hollow microspheres with a 1.5% ratio of iron over titanium because of the smallest size and the highest surface area.

关键词

Keywords

references

Views

271

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Preparation of C/TiO2-SO42- and their water splitting performance

Synthesis of high purity TiO2 powders by fluidized gas hydrolysis

Three-dimensional ordered macro/mesoporous TiO2 inverse opal electrode with enhanced dye-sensitized solar cells' efficiency

Adsorption performance and photocatalytic activity of H3PW12O40 doped titanium dioxide photocatalyst

Properties and structures of modified PVDF ultrafiltration membranes for oily sewage treatment from coastal oil depot

Related Author

WANG Mingxing

LIU Lulu

REN Chao

YANG Renchun

TENG Xuegang

ZHAO Yuzhong

SUN Jianjun

LI Jun

Related Institution

School of Biological and Chemical Engineering, Anhui Polytechnic University

State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academic Sciences

College of Chemical Engineering, Beijing University of Chemical Technology

College of Science, China University of Petroleum, Changping, Beijing 1002249

Beijing Key Laboratory of Optical Detection Technology for Oil and Gas, China University of Petroleum

⁰

Preparation and properties of iron doped TiO2 hollow microspheres

DOI：10.11949/j.issn.0438-1157.20160443

摘要

Abstract

关键词

Keywords

references

Preparation and properties of iron doped TiO₂ hollow microspheres