CHAI Lihong, XIAO Changfa, QUAN Quan, et al. Membrane fouling and dealing with domestic sewage in MBR of homogeneous enhanced PMIA hollow fiber membranes[J]. CIESC Journal, 2016, (9): 3954-3964.
DOI:
CHAI Lihong, XIAO Changfa, QUAN Quan, et al. Membrane fouling and dealing with domestic sewage in MBR of homogeneous enhanced PMIA hollow fiber membranes[J]. CIESC Journal, 2016, (9): 3954-3964.DOI: 10.11949/j.issn.0438-1157.20160059.
Membrane fouling and dealing with domestic sewage in MBR of homogeneous enhanced PMIA hollow fiber membranes
The fouling mechanisms of the homogeneous enhanced aromatic poly(m-phenyleneisophthalamide) (PMIA) hollow fiber membranes were determined by experimental data fitting to pore blocking model or cake fouling model
and combined with the membrane pore size distribution
particle size distribution of filter mediums and the membrane resistance distribution during ultrafiltration. Three materials (CaCO3 suspension
activated sludge and BSA solution) which could induce fouling were used to be filter mediums. In addition
homogeneous enhanced PMIA hollow fiber membranes were applied to membrane bioreactor (MBR) system to deal with domestic sewage. At the meantime
the cleaning effects of water and chemical were analyzed by field emission scanning electron microscopy (FESEM)
and the change of quality fraction of inorganic elements after fouling and cleaning of membrane outer surface was performed by energy dispersive X-ray spectrometer (EDX). The results showed that when the filter medium was BSA
the linear correlation coefficient (t-t/V) was 0.9940. Thus
the main type of the membrane fouling in ultrafiltration of BSA solution was attributed to pore blocking. Owing to the linear correlation coefficient(V-t/V) was 0.9733 and 0.9994
respectively
the membrane fouling caused by CaCO3 suspension and activated sludge was conformed to cake layer formation. Moreover
the MBR operating results showed that the average removal of COD
NH4+-N and TP was up to 97.78%
96.71% and 49.81%
respectively
being beneficial to improve the effluent quality. Furthermore
the chemical cleaning experiment demonstrated that the kinds of inorganic elements of the membrane outer surface were close to the original film. The pollutants were easier to be removed by chemical cleaning.