O2 generation path in Fe2+/H2O2 system

ZHAO Haiqian; GAO Xingcun; WANG Zhonghua; GAO Jihui

doi:10.11949/j.issn.0438-1157.20151820

您当前的位置：

首页 >

文章列表页 >

O₂ generation path in Fe²⁺/H₂O₂ system

更新时间：2025-11-26

- O₂ generation path in Fe²⁺/H₂O₂ system
- CIESC Journal Issue 6, Pages: 2625-2630(2016)
- 作者机构：
  
  1. 东北石油大学土木建筑工程学院,黑龙江,大庆,163318
  2. 哈尔滨工业大学能源科学与工程学院,黑龙江,哈尔滨,150001
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20151820
  CLC： 643
- Online First：05 June 2016，
  
  Published：05 June 2016
- 稿件说明：
移动端阅览
ZHAO Haiqian, GAO Xingcun, WANG Zhonghua, et al. O₂ generation path in Fe²⁺/H₂O₂ system[J]. CIESC Journal, 2016, (6): 2625-2630. DOI: 10.11949/j.issn.0438-1157.20151820.
DOI：

ZHAO Haiqian, GAO Xingcun, WANG Zhonghua, et al. O₂ generation path in Fe²⁺/H₂O₂ system[J]. CIESC Journal, 2016, (6): 2625-2630. DOI: 10.11949/j.issn.0438-1157.20151820. DOI：

摘要

掌握Fe2+/H2O2体系O2的生成路径

可为避免H2O2无效分解

开发经济高效的Fe2+/H2O2体系利用技术指明方向。采用添加自由基捕获剂的方法

探究Fe2+/H2O2体系内各种自由基对O2生成速率的影响

进而确定O2的生成路径。结果表明:Fe2+/H2O2体系内不会产生大量O2-·

O2-·不是生成O2的主要反应物质;O2-·被全部捕获后

体系中仍产生大量O2-·

但此时无O2生成

证明生成O2的反应由·OH和HO2·两种自由基直接参与。分析认为反应·OH+HO2·-H2O+O2是体系内O2生成的主要路径。控制Fe2+/H2O2体系定向生成·OH

抑制HO2·的产生

是提高Fe2+/H2O2体系中H2O2利用率的有效手段。

Abstract

It is important to understand the O2 generation path in Fe2+/H2O2 system to avoid invalid decomposition of H2O2 and to reduce the cost of pollutants degradation technology using Fe2+/H2O2 system. In this paper

radical scavengers were adopted to investigate the roles of different radicals on the generation of O2 in Fe2+/H2O2 system. The results showed that there were few O2-· in Fe2+/H2O2 system

and O2-· was not the main reagent to generate O2. After ·OH was captured

the generation rate of HO2· was still high

however

there was no O2 generation. This indicated that ·OH and HO2· took part in the reaction to generate O2 directly. ·OH+HO2·-H2O O2 is the main reaction path to generate ;O2. Controling H2O2 decomposition path towards ·OH and restraining the production of HO2· were the effective ways to increase the utilization rate of H2O2.

关键词

Keywords

references

Views

169

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Indirect sulfation characteristics of limestone under O2/H2O combustion atmosphere

Combustion characteristics of syngas under oxygen steam conditions

Preparation of Fe3O4/P(GMA-co-EGDMA)magnetic composite microspheres with high specific surface area by deposition of porous template

Influences of Fe2+/Fe3+ and Mn2+ on total nitrogen removal and nitrogen transformations during low-oxygen aeration

Effect of ceramic matrices on dispersion of loaded catalyst and DeNOx activity of catalytic filters

Related Author

XU Minghou

ZHANG Penghui

GUO Junzhe

LÜ Chen

LIU Xiaowei

SUN Shaozeng

MENG Shun

QIN Yukun

Related Institution

State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology

School of Energy Science and Engineering, Harbin Institute of Technology

National Engineering Laboratory for Reducing Emissions from Coal Combustion

Department of Applied Chemistry, College of Science, Northwestern Polytechnical University, Xi’

College of Environmental and Energy Engineering, Beijing University of Technology

⁰