Photocatalytic oxidation desulfurization by iron phthalocyanine supported on Ti-MCM-41

ZHANG Juan; HU Yanhui; REN Tengjie; LI Weikang; ZHAO Dishun

doi:10.11949/j.issn.0438-1157.20150863

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Photocatalytic oxidation desulfurization by iron phthalocyanine supported on Ti-MCM-41

更新时间：2025-12-10

- Photocatalytic oxidation desulfurization by iron phthalocyanine supported on Ti-MCM-41
- CIESC Journal Issue 9, Pages: 3437-3443(2015)
- 作者机构：
  
  河北科技大学化学与制药工程学院,河北,石家庄,050018
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20150863
  CLC： 623.83
- Online First：05 September 2015，
  
  Published：05 September 2015
- 稿件说明：
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ZHANG Juan, HU Yanhui, REN Tengjie, et al. Photocatalytic oxidation desulfurization by iron phthalocyanine supported on Ti-MCM-41[J]. CIESC Journal, 2015, (9): 3437-3443.
DOI：

ZHANG Juan, HU Yanhui, REN Tengjie, et al. Photocatalytic oxidation desulfurization by iron phthalocyanine supported on Ti-MCM-41[J]. CIESC Journal, 2015, (9): 3437-3443. DOI： 10.11949/j.issn.0438-1157.20150863.

摘要

合成了钛硅分子筛Ti-MCM-41

通过对Ti-MCM-41改性以共价键将带有不同取代基的酞菁铁负载于Ti-MCM-41上制备出Ti-MCM-41负载酞菁铁催化剂

并利用红外光谱、X射线衍射、扫描电镜以及BET氮气吸附-脱附等温线以及紫外-可见吸收光谱对合成的催化剂进行表征。在常温常压下

以Ti-MCM-41负载酞菁铁为光催化剂

空气为氧化剂

己内酰胺四丁基溴化铵离子液体为萃取剂

可见光下催化氧化二苯并噻吩(DBT)

采用单一变量法探索该体系的最佳反应条件。结果表明

Ti-MCM-41负载氨基酞菁铁具有较好的光催化活性

且在最佳工艺条件下

DBT的脱除率最高可达95.6%。催化剂重复使用5次后

催化活性没有明显下降。

Abstract

Titanium-silicium molecular sieve Ti-MCM-41 was synthesized and the iron phthalocyanines(FePcs) with different substituent groups were loaded onto the modified Ti-MCM-41 by covalent bond to prepare FePcs(R)/Ti-MCM-41 catalyst. FePcs(R)/Ti-MCM-41 were characterized by FT-IR

XRD

SEM

BET and UV-Vis DRS. Dibenzothiophene(DBT) was photo-oxidized with FePcs(R)/Ti-MCM-41 as photocatalysts

air as oxidant and CPL-CTAB ionic liquid as extraction agent in the irradiation of visible light under room temperature and atmosphere. The optimal reaction conditions were explored by simple variable method. The results showed that FePc(NH2)/Ti-MCM-41 exhibited a better photocatalytic activity and the removal ratio of DBT was up to 95.6% under the optimal reaction conditions. The catalytic performance of FePc(NH2)/Ti-MCM-41 did not decrease obviously after reusing 5 runs of oxidation.

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