Acid-base synergistic effect promoted cycloaddition reaction from CO<sub>2</sub> with epoxide in homogenous catalysis systems

LUO Rongchang; ZHOU Xiantai; YANG Zhi; ZHANG Wuying; JI Hongbing

doi:10.11949/j.issn.0438-1157.20150749

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Acid-base synergistic effect promoted cycloaddition reaction from CO₂ with epoxide in homogenous catalysis systems

更新时间：2025-12-10

- Acid-base synergistic effect promoted cycloaddition reaction from CO₂ with epoxide in homogenous catalysis systems
- CIESC Journal Issue 1, Pages: 258-276(2016)
- 作者机构：
  
  中山大学化学与化学工程学院,广东,广州,510275
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20150749
  CLC： Q028.8
- Online First：05 January 2016，
  
  Published：05 January 2016
- 稿件说明：
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LUO Rongchang, ZHOU Xiantai, YANG Zhi, et al. Acid-base synergistic effect promoted cycloaddition reaction from CO₂ with epoxide in homogenous catalysis systems[J]. CIESC Journal, 2016, (1): 258-276. DOI: 10.11949/j.issn.0438-1157.20150749.
DOI：

LUO Rongchang, ZHOU Xiantai, YANG Zhi, et al. Acid-base synergistic effect promoted cycloaddition reaction from CO₂ with epoxide in homogenous catalysis systems[J]. CIESC Journal, 2016, (1): 258-276. DOI: 10.11949/j.issn.0438-1157.20150749. DOI：

摘要

基于“可持续发展”和“绿色化学”的概念

近年来CO2的捕获、储存及资源化利用在工业上和学术上一直备受关注。通过具有100%原子经济性特点的CO2与环氧化物环加成反应合成五元环状碳酸酯是最有前景的方法之一。基于均相催化剂的设计思想与方法

以CO2和环氧化物的活化本质出发

从催化剂结构的角度综述了均相体系中酸碱协同催化CO2与环氧化物环加成反应合成环状碳酸酯的研究进展

包括简单二元催化体系、功能型一元催化体系和金属配合物催化体系等。

Abstract

In terms of the so-called “sustainable society” and “green chemistry” concepts

carbon dioxide capture

storage and utilization have been attracted much attention from both industrial and academic viewpoints in recent years. The synthesis of five-membered cyclic carbonates via the 100% atom-economical cycloaddition of epoxides with CO2 under mild condition is one of the most promising ways. Herein

based on the design idea of homogenous catalysts

the research advance of the acid-base synergistic effect promoted the cycloaddition reaction from CO2 and epoxide is reviewed from the perspective of catalyst structure

including simple binary catalytic systems

functionalized one-component catalytic systems and metal complexes catalytic systems etc.

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Acid-base synergistic effect promoted cycloaddition reaction from CO2 with epoxide in homogenous catalysis systems

DOI：10.11949/j.issn.0438-1157.20150749

摘要

Abstract

关键词

Keywords

references

Acid-base synergistic effect promoted cycloaddition reaction from CO₂ with epoxide in homogenous catalysis systems