Synthesis and characterization of side aminopolysiloxane modifiedpolyurethane textile coatings

LEI Haibo; LUO Yunjun; FENG Lijuan; WANG Baoyi

doi:10.11949/j.issn.0438-1157.20150421

您当前的位置：

首页 >

文章列表页 >

Synthesis and characterization of side aminopolysiloxane modifiedpolyurethane textile coatings

更新时间：2025-12-10

- Synthesis and characterization of side aminopolysiloxane modifiedpolyurethane textile coatings
- CIESC Journal Issue 11, Pages: 4710-4715(2015)
- 作者机构：
  
  1. 潍坊科技学院山东半岛蓝色经济工程研究院,山东,潍坊,262700
  2. 北京理工大学材料科学与工程学院,北京,100081
  3. 中国科学院高能物理研究所, 核分析技术重点实验室,北京,100049
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20150421
  CLC： Q314.2
- Online First：05 November 2015，
  
  Published：05 November 2015
- 稿件说明：
移动端阅览
LEI Haibo, LUO Yunjun, FENG Lijuan, et al. Synthesis and characterization of side aminopolysiloxane modifiedpolyurethane textile coatings[J]. CIESC Journal, 2015, (11): 4710-4715.
DOI：

LEI Haibo, LUO Yunjun, FENG Lijuan, et al. Synthesis and characterization of side aminopolysiloxane modifiedpolyurethane textile coatings[J]. CIESC Journal, 2015, (11): 4710-4715. DOI： 10.11949/j.issn.0438-1157.20150421.

摘要

以侧氨基聚硅氧烷(SAPDMS)、聚四氢呋喃醚、聚乙二醇为混合软段

二羟甲基丙酸为亲水扩连剂

4-丁二醇为硬段调节剂

与异佛尔酮二异氰酸酯反应合成了水性有机硅改性聚氨酯(WSSPU)

并以WSSPU为基础制备了防水透湿织物涂层剂。分别采用红外光谱、差热扫描量热仪、动态力学分析仪、正电子湮灭寿命谱等表征了WSSPU膜的组成与微观结构

考察了WSSPU膜的力学性能和涂层织物的防水透湿性能。结果表明

当侧氨基聚硅氧烷用量(质量比)< 15%时

可以制得稳定的乳液。聚硅氧烷改性后膜内部微相分离结构更加明显

自由体积空洞变大

透湿性能提高。

Abstract

The water-borne side aminopolysiloxane modified polyurethanes (WSSPU) were prepared by polyaddition reaction using poly(tetramethylene oxide)glycol

polyethylene glycol

and side aminopolysiloxane as soft segments

dimethylolpropionic acid as hydrophilic chain extender

4-butanediol as hard segment regulator and isophorone diisocyanate. The waterproof and moisture permeable textile coating agent was then fabricated based on WSSPU. The chemical composition and microstructure of WSSPU were characterized by infrared spectroscopy

differential scanning calorimetry

dynamic mechanical analyzer and positron annihilation lifetime spectroscopy

respectively. The mechanical properties of WSSPU films

the waterproofness and breathability of the coated fabric were determined. The results showed that the stable emulsion can be obtained at the amount of SAPDMS (mass ratio) below 15%. The modified polyurethane membranes had more serious micro-phase separation structure and increased free hole volume

resulting in improved moisture permeability.

关键词

Keywords

references

Views

254

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Research progress on high and low temperature performance and influencing factors of polyurethane modified asphalt

Preparation and property of waterborne polyurethane-based ITO etching ink

Preparation and characterization of carboxylate/sulfonate composite WPU emulsion adhesive

Synthesis and properties of novel TMPPs/non-ionic waterborne polyurethane

Methods of adaptive prediction and abnormal states traceability for sulphur content in flue gas desulfurization process

Related Author

GUO Naisheng

ZHU Xiaobo

WANG Shuang

CHEN Ping

CHU Zhaoyang

WANG Zhichen

HUANG Jiajian

ZHONG Yingli

Related Institution

College of Transportation Engineering, Dalian Maritime University

School of Computer Science and Engineering, Hunan University of Information Technology

Intelligent Engineering Technology Research Center, Harbin Cambridge University

College of Materials and Energy, South China Agricultural University

School of Chemistry and Chemical Engineering, South China University of Technology

⁰