LU Hanfeng, HUANG Jinxing, ZHOU Ying, et al. Effect of precipitants on structure and performance of Cu-Mn-Ce mixed oxide catalysts[J]. CIESC Journal, 2015, (6): 2105-2111.
DOI:
LU Hanfeng, HUANG Jinxing, ZHOU Ying, et al. Effect of precipitants on structure and performance of Cu-Mn-Ce mixed oxide catalysts[J]. CIESC Journal, 2015, (6): 2105-2111.DOI: 10.11949/j.issn.0438-1157.20141930.
Effect of precipitants on structure and performance of Cu-Mn-Ce mixed oxide catalysts
Cu-Mn-Ce(CMC) ternary mixed oxides were prepared by the co-precipitation method with different precipitants
and evaluated in catalytic combustion of toluene. The catalyst prepared with NaOH(CMC-NaOH)exhibited the highest catalytic activity
followed by the catalyst prepared with NH3•H2O
K2CO3
and Na2C2O4. The precursors of hydroxide derived from NaOH had strong interaction
and Cu
Mn ions more easily entered the lattice of CeO2 fluorite structure to form CeO2 solid solution during calcination. As a result
the structure containing Cu-Mn mixed oxides and CeO2 solid solution enhanced the mobility of active oxygen owing to abundant defective sites on the surface