MA Qinglan, LEI Yahui, CHEN Guangjin. Simulation of absorption-hydration separation unit for gas mixture by non-equilibrium stage approach[J]. CIESC Journal, 2015, (5): 1748-1759.
DOI:
MA Qinglan, LEI Yahui, CHEN Guangjin. Simulation of absorption-hydration separation unit for gas mixture by non-equilibrium stage approach[J]. CIESC Journal, 2015, (5): 1748-1759.DOI: 10.11949/j.issn.0438-1157.20141195.
Simulation of absorption-hydration separation unit for gas mixture by non-equilibrium stage approach
It has been accepted that separation of low boiling-point gas mixture via hydrate technology has the advantage of operating at around 0℃
and therefore can reduce the refrigerating energy consumption dramatically. It is necessary to study the simulation algorithm for the operation process because this separation technique is still at the stage of theoretical research and has not fulfilled practical industrial application. In this work
a process of hydration and absorption two-tower series operation was simulated by using the non-equilibrium stage approach
which involved hydrate formation kinetic model
hydrate dissociation kinetic model
and mass transfer kinetic model when gas was absorbed in water-in-oil emulsion. The effect of operation parameters of two series towers
such as temperature
pressure on separation efficiency was investigated. The calculation results are of significance for designing separation process for low boiling-point gas mixture via hydrate technology
and can also lay a theoretical foundation for industrial application of this separation technique.